[Re(CO)3Br(4-(5-diphenylaminopyrimidin-2-ylethynyl)benzonitrile)]2 | 880266-43-3

• 英文名称: [Re(CO)3Br(4-(5-diphenylaminopyrimidin-2-ylethynyl)benzonitrile)]2
• CAS: 880266-43-3
• 化学式: C₅₆H₃₂Br₂N₈O₆Re₂
• 分子量: 1445.14
• InChiKey: BEOCZEOWHKMZLY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-(5-diphenylaminopyrimidin-ylethynyl)benzonitrile 、 [ReBr(CO)3(thf)]2 以 四氢呋喃 为溶剂， 以67%的产率得到[Re(CO)3Br(4-(5-diphenylaminopyrimidin-2-ylethynyl)benzonitrile)]2
  参考文献：
  名称：

  Self-assembly molecular architectures with novel cyclic dimers

  摘要：

  Highly emissive conjugated compounds containing pyridine (or pyrimidine) and cyano ligands have been synthesized by palladium-catalyzed cross-coupling reaction. These ligands readily react with Re(CO)(3)(THF)(2)Br to form cyclic supramolecules by self-assembly processes. At room temperature these supramolecules are emissive, and the emission is ligand-localized, as evidenced from the Stokes shift and the lifetime data. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.10.046