(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)bromochloro(2,4,6-triisopropylphenyl)germane | 162088-71-3

• 英文名称: (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)bromochloro(2,4,6-triisopropylphenyl)germane
• CAS: 162088-71-3
• 化学式: C₄₂H₈₂BrClGeSi₆
• 分子量: 943.573
• InChiKey: VKVWBQFBTUWTKM-UHFFFAOYSA-N

物化性质

• 沸点：
  671.9±65.0 °C(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)bromochloro(2,4,6-triisopropylphenyl)germane 在 NH₄Cl 作用下， 以 四氢呋喃 、 水 为溶剂， 生成 5-(2,4,6-tris(bis(trimethylsilyl)methyl)phenyl)-5-(2,4,6-triisopropylphenyl)-1,2,3,4,5-tetrathiagermolane
  参考文献：
  名称：

  Synthesis and Structure of Novel Germanium-Containing Cyclic Polysulfides

  摘要：

  Novel germanium-containing cyclic polysulfides 1,2,3,4,5-tetrathiagermolane 5 (Tbt(Ar)GeS4; Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl; Ar = mesityl, 2,6-diethylphenyl, 2,4,6-triisopropylphenyl) have been synthesized, and the molecular structure of Tbt(Mes)GeS4 was determined by X-ray crystallographic analysis. Reaction of the tetrathiagermolanes 5 with diphenyldiazomethane gave 1,2,3,5-tetrathia-4-germacyclopentanes 10, 1,2,4,5-tetrathia-3-germacyclohexanes 11, and 1,2,4-trithia-3-germacyclopentanes 12. The structure of 1,2,3,5-tetrathia-4-germacyclohexane 10a was determined by X-ray structural analysis.

  DOI：

  10.1021/om00002a055
• 作为产物：
  描述：

  四氯化锗 、 1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene 、 magnesium,1,3,5-tri(propan-2-yl)benzene-6-ide,bromide 在 t-BuLi 、 NH₄Cl 作用下， 以 四氢呋喃 、 正戊烷 为溶剂， 以66%的产率得到(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)bromochloro(2,4,6-triisopropylphenyl)germane
  参考文献：
  名称：

  Synthesis and Structure of Novel Germanium-Containing Cyclic Polysulfides

  摘要：

  Novel germanium-containing cyclic polysulfides 1,2,3,4,5-tetrathiagermolane 5 (Tbt(Ar)GeS4; Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl; Ar = mesityl, 2,6-diethylphenyl, 2,4,6-triisopropylphenyl) have been synthesized, and the molecular structure of Tbt(Mes)GeS4 was determined by X-ray crystallographic analysis. Reaction of the tetrathiagermolanes 5 with diphenyldiazomethane gave 1,2,3,5-tetrathia-4-germacyclopentanes 10, 1,2,4,5-tetrathia-3-germacyclohexanes 11, and 1,2,4-trithia-3-germacyclopentanes 12. The structure of 1,2,3,5-tetrathia-4-germacyclohexane 10a was determined by X-ray structural analysis.

  DOI：

  10.1021/om00002a055