[((dl-mandelate)Me2Sn)2O] | 225117-91-9

• 英文名称: [((dl-mandelate)Me2Sn)2O]
• CAS: 225117-91-9
• 化学式: C₂₀H₂₆O₇Sn₂
• 分子量: 615.842
• InChiKey: OGUVHADLMXJOTI-CYMVYQPSSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二甲基氧化锡 、 扁桃酸 以 乙醇 为溶剂， 生成 [((dl-mandelate)Me2Sn)2O]
  参考文献：
  名称：

  摘要：

  The compounds [(LR2Sn)(2)O] {R=CH3 (Me), n-C4H9 (B-n); L=C6H5CH(OH)COO-} were studied by thermogravimetric and differential scanning calorimetry in a dynamic atmosphere of helium. The thermal decomposition mechanisms are similar for both compounds and occur in two consecutive steps. The TG curves of the complexes suggest the liberation of the ligand L in the first step, with probable formation of a tin oxide R2SnO intermediate. At the end of the second step free tin is obtained in accordance with the stoichiometry of the related compounds. An inverse relation between DeltaH(fusion) and solubility of the compounds suggests a polymeric structure for the compound with B-n ligand in relation to the compound with M ligand.

  DOI：

  10.1023/a:1013988930942