SnCl2(dimethyldithiocarbamate)2 | 127420-28-4

• 英文名称: SnCl2(dimethyldithiocarbamate)2
• 英文别名: cis-dichlorobis(N,N-diethyldithiocarbamato)tin(IV)
• CAS: 127420-28-4；22041-64-1；22804-28-0；22845-85-8；61816-78-2
• 化学式: C₆H₁₂Cl₂N₂S₄Sn
• 分子量: 430.055
• InChiKey: YENFFAYDKWGXCE-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  sodium diethyldithiocarbamate trihydrate 、 tin(ll) chloride 以 四氢呋喃 为溶剂， 生成 SnCl2(dimethyldithiocarbamate)2
  参考文献：
  名称：

  Characterization of an unusual reaction product of tin(II) chloride with sodium N,N-diethyldithiocarbamate

  摘要：

  The reaction of sodium N,N-diethyldithiocarbamate trihydrate with tin(II) chloride under aerobic conditions yields the unexpected cis-dichlorobis(N,N-diethyldithiocarbamato)tin(IV) which has been characterized by X-ray crystallography. This illustrates the tin to be in a distorted octahedral configuration; the coordination valencies being provided by the two chlorines in cis positions and two dithiocarbamates in cis-orientations. The Sn-119 NMR of the complex is consistent with the presence of six coordinated tin(IV). The formation of the complex is explained via the intermediate product, tetraethylthiuram disulphide.

  DOI：

  10.1016/s0277-5387(00)83008-9

文献信息

• Jalil, N. S. Neelam, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1989, vol. 19, p. 1069 - 1084
  作者：Jalil, N. S. Neelam

  DOI：——

  日期：——