| 748189-39-1

• CAS: 748189-39-1
• 化学式: C₂₈H₃₃ClO₂PRu*F₆P
• 分子量: 714.03
• InChiKey: RIONMOYTPOPUKT-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  3-氯丙烯 、 (S)-[ruthenium(2-methyl-4-(C(CH3)3)-1-(COOCH2CH2P(phenyl)2))cyclopentadienyl)(CH3CN)2]PF6 以 丙酮 为溶剂， 以81%的产率得到
  参考文献：
  名称：

  Diastereoselective Oxidative Addition of Allyl Chloride to Planar-Chiral Cyclopentadienyl−Ruthenium Complexes

  摘要：

  The reaction of planar-chiral cyclopentadienyl-ruthenium complexes with allyl chloride at room temperature resulted in the diastereoselective formation of pi-allyl-ruthenium complexes, in which the chirality at the Ru center depended on the substituent at the 4-position of the cyclopentadienyl group. Epimerization at the Ru center of pi-allyl complexes at 90 degreesC suggested that the diastereoselectivity was under kinetic control.

  DOI：

  10.1021/om049616d