(tri(1-cyclohepta-2,4,6-trienyl)phosphane)Pd(S2C2B10H10) | 460739-85-9

• 英文名称: (tri(1-cyclohepta-2,4,6-trienyl)phosphane)Pd(S2C2B10H10)
• CAS: 460739-85-9
• 化学式: C₂₃H₃₁B₁₀PPdS₂
• 分子量: 617.135
• InChiKey: KEYXUUIEDWCCFJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,2,3,4,5,6,7,8-八硫杂环辛烷 、 1,2-dicarba-closo-dodecaborane(12) 、 [(di(1-cyclohepta-2,4,6-trienyl)(η(2)-1-cyclohepta-2,4,6-trienyl)phosphine)PdCl2] 在 n-BuLi 作用下， 以 四氢呋喃 、 乙醚 、 正己烷 为溶剂， 以66%的产率得到(tri(1-cyclohepta-2,4,6-trienyl)phosphane)Pd(S2C2B10H10)
  参考文献：
  名称：

  Platinum(II) and Palladium(II) Bis(chelate) Complexes Containing both Tri(1-cyclohepta-2, 4, 6-trienyl)phosphane, P(C7H7)3, and Dichalcogenolato LigandsDedicated to Professor Joachim Strähle on the Occasion of his 65th Birthday

  摘要：

  Tri(1-cyclohepta-2,4,6-trienyl)phosphane, P(C7H7)(3) ([P] when coordinated to a metal atom), was used to stabilize complexes of platinum(II) and palladium(II) with chelating dichalcogenolato ligands as [P]M(Eboolean ANDE) [E = S, boolean AND = CH2CH2, M = Pt (3a); E = S, boolean AND = 1,2-C6H4, M = Pt (5a), Pd (6a) E = S, boolean AND = C(O)C(O), M = Pt (7a), Pd (8a); E = S, Se, boolean AND = 1,2-C-2(B10H10), M = Pt (9a, 9b), Pd (10a, 10b); E = S, boolean AND = Fe-2(CO)(6), M = Pt (11a), Pd (12a)]. Starting materials in all reactions were [P]MCl2 with M = Pt (1) and Pd (2). Attempts at the synthesis of [P]M(ER)(2) with non-chelating chalcogenolato ligands were not successful. All new complexes were characterized by multinuclear magnetic resonance spectroscopy in solution (H-1, C-13, P-31, Se-77 and Pt-195 NMR), and the molecular structures of 5a and 12a were determined by X-ray analysis. Both in the solid state and in solution the ligand [P] is linked to the metal atom by the P-M bond and by eta(2)-C=C coordination of the central C=C bond of one of the C7H7 rings. In solution, intramolecular exchange between coordinated and non-coordinated C7H7 rings is observed, the exchange process being markedly faster in the case of M = Pd than for M = Pt.

  DOI：

  10.1002/1521-3749(200206)628:5<979::aid-zaac979>3.0.co;2-l