| 156843-09-3

• CAS: 156843-09-3
• 化学式: C₄₄H₄₈PRu₂S₂*F₆P
• 分子量: 1019.08
• InChiKey: OUSYKOLPMODXNQ-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  、 苯硫酚 以 四氢呋喃 为溶剂， 以18%的产率得到
  参考文献：
  名称：

  Synthesis and derivative chemistry of [Ru2(μ-PPh2) (μ-OH) 2(μ6-p-cymene) 2]+

  摘要：

  The cationic diphenylphosphido-bridged compound [Ru2(mu-PPh2)(mu-OH)2(eta6-p-cymene)2][PF6] (2) has been prepared by reaction of the tri-mu-hydroxo complex [Ru2(mu-OH)3(eta6-p-cymene)2][PF6] (1) with diphenylphosphine. Complex 2 eliminates water on reaction with protic acids, incorporating the conjugate base of the added acid as a bridging ligand. Formic acid, acetic acid, phenol, and aniline react with 2 to give the monosubstituted compounds [Ru2(mu-PPh2)(mu-OH)(mu-L)(eta6-p-cymene)2][PF6] (L = HCO2, MeCO2, OPh, or NHPh), whereas methanol, thiophenol, 1,2-benzenedithiol, hydrochloric acid and isopropanol afford the disubstituted derivatives [Ru2(mu-PPh2)(mu-L)2 (eta6-p-cymene)2][PF6] (L = OMe, SPh, 1/2 S2C6H4, Cl, or H).

  DOI：

  10.1016/0022-328x(94)80163-0