| 137892-85-4

• CAS: 137892-85-4
• 化学式: C₂₅H₄₅FeHgIN₅*ClO₄
• 分子量: 898.458
• InChiKey: JRTMXHCAEXJZPF-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  在 AgCl 作用下， 以 丙酮 为溶剂， 以59%的产率得到
  参考文献：
  名称：

  Insertion of mercury into iron–halogen bonds. X-Ray structure of [(p-MeC₆H₄NC)₅Fe → HgI₂]

  摘要：

  The complexes [Fel2(CNR)4] (R = Ph, p-MeC6H4 or Bu(t)) react with Hg in the presence of CNR to give [(RNC)5Fe --> Hgl2], and exchange reactions with AgX (X = Br or Cl) lead to the corresponding halogeno-complexes [(RNC)5Fe --> HgX2]. Treatment with 1 mol of AgClO4 affords the cationic complexes [(RNC)5Fe-HgX]ClO4 which are unstable towards mercury extrusion. The relative stability of the complexes is discussed in terms of the influence of the lignads co-ordinated to Hg and the steric and electronic characteristics of the RNC ligands. The structure of [(p-MeC6H4NC)5Fe --> Hgl2] has been determined: monoclinic, space group P2(1)/a, a = 16.680(3), b = 18.031 (4), c = 15.256(2) angstrom, beta = 116.92(2)-degrees and Z = 4.

  DOI：

  10.1039/dt9910002503
• 作为产物：
  描述：

  以 四氢呋喃 、 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Insertion of mercury into iron–halogen bonds. X-Ray structure of [(p-MeC₆H₄NC)₅Fe → HgI₂]

  摘要：

  The complexes [Fel2(CNR)4] (R = Ph, p-MeC6H4 or Bu(t)) react with Hg in the presence of CNR to give [(RNC)5Fe --> Hgl2], and exchange reactions with AgX (X = Br or Cl) lead to the corresponding halogeno-complexes [(RNC)5Fe --> HgX2]. Treatment with 1 mol of AgClO4 affords the cationic complexes [(RNC)5Fe-HgX]ClO4 which are unstable towards mercury extrusion. The relative stability of the complexes is discussed in terms of the influence of the lignads co-ordinated to Hg and the steric and electronic characteristics of the RNC ligands. The structure of [(p-MeC6H4NC)5Fe --> Hgl2] has been determined: monoclinic, space group P2(1)/a, a = 16.680(3), b = 18.031 (4), c = 15.256(2) angstrom, beta = 116.92(2)-degrees and Z = 4.

  DOI：

  10.1039/dt9910002503