| 181273-20-1

• CAS: 181273-20-1
• 化学式: C₂₇H₂₄ClO₂PRu
• 分子量: 547.983
• InChiKey: BJOLMWXULTUDIO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 四乙烯基锡 在 copper(l) chloride 作用下， 以 四氢呋喃 为溶剂， 以67%的产率得到[C5H5Ru((2-4-η)-CH2CHC=CHCO2Me)(PPh3)]
  参考文献：
  名称：

  [(2−4-η)-Butadienyl]- and [(3−5-η)-Pentatrienyl]ruthenium Complexes from Vinylidene and Allenylidene Precursors¹

  摘要：

  The vinylideneruthenium complex [C5H5RuCl(=C=CHCO(2)Me)(PPh(3))] (2), which is obtained on stepwise treatment of [C(5)H(5)RU(eta(3)-C(3)H(4)Me)(PPh(3))] (1) with HC=CCO(2)Me and HCl in aromatic solvents, reacts with Sn(CH=CH2)(4) in the presence of CuCl to give the (2-4-eta)-butadienyl compound [C(5)H(5)RU(eta(3)-CH2CHC=CHCO(2)Me)] (3) in, about 70% yield. A similar C-C coupling reaction Leading to the formation of the (3-5-eta)-pentatrienyl metal complex [C5H5Ru{(3-5-eta)-CH2CHC=C=CPh(2)}(PPh(3))] (5) occurs on treatment of the allenylidene compound [C(5)Me(5)RuCl(=C=C=CPh(2)){kappa(P)-iPr(2)PCH(2)CO(2)Me}] (4) with CH2=CHMgBr in C6H6/THF.

  DOI：

  10.1021/om960390r
• 作为产物：
  描述：

  盐酸 、 [C5H5Ru(η(3)-C3H4Me)(PPh3)] 、 丙炔酸甲酯 以 甲苯 、 苯 为溶剂， 以94%的产率得到
  参考文献：
  名称：

  [(2−4-η)-Butadienyl]- and [(3−5-η)-Pentatrienyl]ruthenium Complexes from Vinylidene and Allenylidene Precursors¹

  摘要：

  The vinylideneruthenium complex [C5H5RuCl(=C=CHCO(2)Me)(PPh(3))] (2), which is obtained on stepwise treatment of [C(5)H(5)RU(eta(3)-C(3)H(4)Me)(PPh(3))] (1) with HC=CCO(2)Me and HCl in aromatic solvents, reacts with Sn(CH=CH2)(4) in the presence of CuCl to give the (2-4-eta)-butadienyl compound [C(5)H(5)RU(eta(3)-CH2CHC=CHCO(2)Me)] (3) in, about 70% yield. A similar C-C coupling reaction Leading to the formation of the (3-5-eta)-pentatrienyl metal complex [C5H5Ru{(3-5-eta)-CH2CHC=C=CPh(2)}(PPh(3))] (5) occurs on treatment of the allenylidene compound [C(5)Me(5)RuCl(=C=C=CPh(2)){kappa(P)-iPr(2)PCH(2)CO(2)Me}] (4) with CH2=CHMgBr in C6H6/THF.

  DOI：

  10.1021/om960390r