[η6-(benzene) ruthenium(II) (chloride)2 (β-picoline)] | 913079-28-4

• 英文名称: [η6-(benzene) ruthenium(II) (chloride)2 (β-picoline)]
• 英文别名: [η6-(benzene) ruthenium(II) (chloride)2 (3-methyl-pyridine)]
• CAS: 913079-28-4
• 化学式: C₁₂H₁₃Cl₂NRu
• 分子量: 343.218
• InChiKey: MXKLPDAWTPTUSE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [RuCl2(benzene)]2 、 3-甲基吡啶 以 甲醇 为溶剂， 以81%的产率得到[η6-(benzene) ruthenium(II) (chloride)2 (β-picoline)]
  参考文献：
  名称：

  Synthesis, molecular, crystal and electronic structure of [(C6H6)RuCl2(picoline)]

  摘要：

  [(C6H6)RuCl2(pic)] complexes have been synthesized by the reaction of [(C6H6)RuCl2](2) with alpha-, beta- and gamma-picoline in methanolic solution. The prepared complexes have been studied by IR, UV-Vis and H-1 NMR spectroscopy. The crystal structure of the complex with alpha-picoline was determined by X-ray crystallography. The electronic spectra of the compounds have been calculated by the TDDFT method. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.02.016