| 1429493-96-8

• CAS: 1429493-96-8
• 化学式: C₃₂H₂₉BN₂O
• 分子量: 468.406
• InChiKey: OAPDNDVAVYUFBL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  5-溴-8-甲氧基喹啉 在 四(三苯基膦)钯 、 三溴化硼 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 90.0h， 生成
  参考文献：
  名称：

  Pyridine-Functionalized Luminescent Organoboron Quinolate Block Copolymers as Versatile Building Blocks for Assembled Nanostructures

  摘要：

  Novel luminescent boron quinolate block copolymers with pyridine functionalities were prepared via RAFT polymerization and employed as building blocks for assembled nanostructures. In selective solvents, the block copolymers self-assembled into vesicles, spherical and extended branched aggregates. Quaternization reactions were performed to modify the solubility of the block copolymers and to prepare a cross-linked polymeric gel. As polymeric Lewis bases, the pyridine-functionalized block copolymers are able to form supramolecular complexes with metal ions and Lewis acids. Coordination to ZnCl2 in chloroform led to spherical micelles or larger aggregates. The supramolecular coassernbly of PS-b-PBQPy-1 and zinc meso-tetraphenylporphyrin (ZnTPP) in cyclohexane as a selective solvent for PS resulted in extended branched structures with controllable emission properties. Energy transfer from the boron chrornophores to the ZnTPP moieties was observed in these supramolecular complexes.

  DOI：

  10.1021/ma400310s