(η8-cyclooctatetraenyl){N,N'-bis(trimethylsilyl)-4-methoxybenzamidinato}(tetrahydrofuran)titanium(III) | 156886-10-1

• 英文名称: (η8-cyclooctatetraenyl){N,N'-bis(trimethylsilyl)-4-methoxybenzamidinato}(tetrahydrofuran)titanium(III)
• CAS: 156886-10-1
• 化学式: C₂₆H₄₁N₂O₂Si₂Ti
• 分子量: 517.675
• InChiKey: GKDMFJHWEAITEE-VNOJDAHOSA-N

反应信息

• 作为产物：
  描述：

  {N,N'-bis(trimethylsilyl)-4-methoxybenzamidinato}lithium 、 {(η8-cyclooctatetraenyl)(μ-Cl)titanium(III)(THF)}2 以 四氢呋喃 为溶剂， 以77%的产率得到(η8-cyclooctatetraenyl){N,N'-bis(trimethylsilyl)-4-methoxybenzamidinato}(tetrahydrofuran)titanium(III)
  参考文献：
  名称：

  Cyclooctatetraenyl-komplexe der frühen Übergangsmetalle und lanthanoide

  摘要：

  [(COT)Ti(mu-CI)(THF)]2 (1) reacts with K[HBpz3] or K[HB(3,5-Me2pz)3] to give the new monocyclooctatetraenyl half-sandwich complexes (COT)Ti[HBPZ3] (2) and (COT)Ti[HB(3,5-Me2PZ)3] (3) respectively, as dark green, air-sensitive solids (COT = eta8-cyclooctatetraenyl(2-)). The molecular structure of 2 has been determined by an X-ray diffraction study. The monomeric organotitanium(III) complexes (COT)Ti[PhC(NSiMe3)2](THF) (4), (COT)Ti[MeOC6H4C(NSiMe3)2)(THF) (5) and (COT)Ti[Ph2P(NSiMe3)2](6) have been prepared by treatment of [(COT)Ti(mu-Cl)(THF)]2 (1) with the corresponding heteroallylic ligands.

  DOI：

  10.1016/0022-328x(94)88082-4