| 227935-95-7

• CAS: 227935-95-7
• 化学式: C₄H₈CeCl₅O*C₂₀H₄₀CeClNO₈
• 分子量: 987.604
• InChiKey: GFAPHGBMSFOGOA-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  三甲基氯硅烷 、 cerium(4+);2-methylpropan-2-olate;oxolane;dinitrate 以 四氢呋喃 为溶剂， 以83%的产率得到
  参考文献：
  名称：

  Chloride abstraction activity of Ce(IV) nitrate and alkoxide complexes: Facile formation of [CeCl5(THF)][CeClZ(THF)5] (Z=NO3, Cl)

  摘要：

  Ce(OCMe3)(2)(NO3)(2)(THF)(2) and Ce(OCMe3)(NO3)(3)(THF)(2) react with chlorotrimethylsilane in tetrahydrofuran (THF) at room temperature to form [CeCl(NO3)(THF)(5)] [CeCl5(THF)], 1, and [CeCl5(THF)(5)][CeCl5 (THF)], 2. Ce(OCMe3)(4)(THF)(2) is less reactive under the same conditions but was found to form a salt involving a [CeCl5(THF)](-) anion. Ceric ammonium nitrate, [(NH4)(2)Ce(NO3)(6)], does not form these polychlorinated species under these conditions. 1 crystallizes from THF to form an octahedral [CeCl5(THF)](-) anion and a pentagonal bipyramidal [CeCl(NO3)(THF)(5)](+) cation, which has chloride and nitrate in the axial positions. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00008-x