| 879556-27-1

• CAS: 879556-27-1
• 化学式: C₄₄H₃₄BF₂O₂P₂Ru*F₆Sb
• 分子量: 1042.32
• InChiKey: KGXNBJMTQMUBDO-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  oxonium hexafluoroantimonate(V) 、 tetrafluoroboric acid 、 Ru(OAc)2((S)-BINAP) 以 水 、 1,2-二氯乙烷 为溶剂， 以81%的产率得到
  参考文献：
  名称：

  Structural studies on novel Ru(II)–Binap complexes

  摘要：

  The solid-state structures for two complexes, 7 and 8, are reported. Complex 7 was prepared by treating Ru(OAc)(2)(Binap) with two equivalents of HBArF in toluene solution, and represents only the second solid-state structure of a Binap, complex, in which the Binap is a 6e donor to the Ru(II). The bonding is maintained in solution as shown via C-13 NMR studies. The unusual cation 8, as an SbF6- salt, arises from prolonged reaction of Ru(OAc)(2)(Binap) with wet HBF4 (and, subsequently, added HSbF6) in 1,2-dichloroethane. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.06.072