chloro(η(5)-cyclopentadienyl)[methylenebis(diphenylphosphine-P)]ruthenium-choroform (1/1) | 177744-90-0

• 英文名称: chloro(η(5)-cyclopentadienyl)[methylenebis(diphenylphosphine-P)]ruthenium-choroform (1/1)
• CAS: 177744-90-0
• 化学式: CHCl₃*C₃₀H₂₇ClP₂Ru
• 分子量: 705.393
• InChiKey: IRCIGKXSXBMVIO-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  双二苯基膦甲烷 、 [CpRu(CO)₂]₂ 以 氯仿 、 正戊烷 为溶剂， 生成 chloro(η(5)-cyclopentadienyl)[methylenebis(diphenylphosphine-P)]ruthenium-choroform (1/1)
  参考文献：
  名称：

  Two Monomeric Ruthenium Complexes Containing Bidentate Bis(diphenylphosphino) Ligands

  摘要：

  The crystal structures of chloro(eta(5)-cyclopentadienyl)-[methylenebis (diphenylphosphine-P)]ruthenium-chloroform (1/1), [RuCl(C5H5)(C25H22P2)].CHCl3, (A), and chloro(eta(5)-cyclopentadienyl)[1,2-ethanediylbis(diphenylphosphine-P)]ruthenium-chloroform (1/1), [RuCl(C5H5)(C26H24P2)].CHCl3, (B), are reported. Both complexes contain a central ring structure in which a pair of P atoms, linked by a -CH2- [in (A)] or a -C2H4- [in (B)] group, are bonded to a central Ru atom. The P-Ru-P bond angle undergoes expansion from 72.07 (2)degrees in (A) to 83.48(2)degrees in (B). The bond distances around the Ru center are compared with values reported for similar compounds. Both structures include a chloroform solvent molecule in addition to the ruthenium complex. The chloroform molecule in (A) was found to be disordered.

  DOI：

  10.1107/s0108270195011802