[Pt(10-[1-Cl,1-ferrocenyl(vinyl)]benzoquinoline-κN-η2)(C6F5)Cl] | 1446102-35-7

• 英文名称: [Pt(10-[1-Cl,1-ferrocenyl(vinyl)]benzoquinoline-κN-η2)(C6F5)Cl]
• CAS: 1446102-35-7
• 化学式: C₃₁H₁₈Cl₂F₅FeNPt
• 分子量: 821.316
• InChiKey: ZJNCQOVOADSSTI-JCBMKOSPSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pt(10-[1-Cl,1-ferrocenyl(vinyl)]benzoquinoline-κN-η2)(C6F5)Cl] 、 三苯基膦 以 二氯甲烷 为溶剂， 反应 1.0h， 以32%的产率得到(Z)-10-[1-Cl,1-ferrocenyl(vinyl)]-benzoquinoline
  参考文献：
  名称：

  Unexpected Formation of Ferrocenyl(vinyl)benzoquinoline Ligands by Oxidation of an Alkyne Benzoquinolate Platinum(II) Complex

  摘要：

  Oxidation of [Pt(bzq-kappa N,kappa C-10)(C6F5)(eta(2)-HC CFc)] (1) with PhICl2 and I-2 affords the unusual halideferrocenyl(vinyl)benzoquinoline Pt-II derivatives [Pt{bzq-kappa N-eta(2)-CH=C(X)Fc}(C6F5)X] (X = Cl (4a), I (4b)), arising from C-X and C-C coupling processes, together with small amounts of the corresponding Pt-IV products [{Pt(bzq-kappa N,kappa C-10)(C6F5)X(mu-X)}(2)] (X = Cl (5a), I (5b), respectively. Complexes 4 are very stable but they undergo easy displacement reactions with PPh3, yielding trans-[Pt(C6F5)X(PPh3)(2)] and the corresponding new functionalized (vinyl)-benzoquinoline ligands [(Z)-bzq-CH=C(X)Fc] (X = Cl (6a), I (6b)). The dinuclear Pt-IV derivatives 5 are alternatively obtained in high yield by oxidation of the solvate [Pt(bzq-kappa N,kappa C-10)(C6F5)(CH3COCH3)] (2). Treatment of 5 with dmso or direct oxidation of [Pt(bzq-kappa N,kappa C-10)(C6F5)(tht)] (3) provides mononuclear [Pt(bzq-kappa N,kappa C-10)(C6F5)X-2(L)] (L = dmso (7a-c), tht (8a-c)) as a mixture of cis and trans isomers.

  DOI：

  10.1021/om4004384
• 作为产物：
  描述：

  (二氯碘)-苯 、 [Pt(7,8-benzo[h]quinolinyl)(pentafluorophenyl)(η²-(ferrocenyl)CCH)] 以 二氯甲烷 为溶剂， 反应 3.0h， 以79%的产率得到[Pt(10-[1-Cl,1-ferrocenyl(vinyl)]benzoquinoline-κN-η2)(C6F5)Cl]
  参考文献：
  名称：

  Unexpected Formation of Ferrocenyl(vinyl)benzoquinoline Ligands by Oxidation of an Alkyne Benzoquinolate Platinum(II) Complex

  摘要：

  Oxidation of [Pt(bzq-kappa N,kappa C-10)(C6F5)(eta(2)-HC CFc)] (1) with PhICl2 and I-2 affords the unusual halideferrocenyl(vinyl)benzoquinoline Pt-II derivatives [Pt{bzq-kappa N-eta(2)-CH=C(X)Fc}(C6F5)X] (X = Cl (4a), I (4b)), arising from C-X and C-C coupling processes, together with small amounts of the corresponding Pt-IV products [{Pt(bzq-kappa N,kappa C-10)(C6F5)X(mu-X)}(2)] (X = Cl (5a), I (5b), respectively. Complexes 4 are very stable but they undergo easy displacement reactions with PPh3, yielding trans-[Pt(C6F5)X(PPh3)(2)] and the corresponding new functionalized (vinyl)-benzoquinoline ligands [(Z)-bzq-CH=C(X)Fc] (X = Cl (6a), I (6b)). The dinuclear Pt-IV derivatives 5 are alternatively obtained in high yield by oxidation of the solvate [Pt(bzq-kappa N,kappa C-10)(C6F5)(CH3COCH3)] (2). Treatment of 5 with dmso or direct oxidation of [Pt(bzq-kappa N,kappa C-10)(C6F5)(tht)] (3) provides mononuclear [Pt(bzq-kappa N,kappa C-10)(C6F5)X-2(L)] (L = dmso (7a-c), tht (8a-c)) as a mixture of cis and trans isomers.

  DOI：

  10.1021/om4004384