(η5-1-trifluoromethyl-2,3,4,5-tetramethylcyclopentadienyl)bis(acetonitrile)monocarbonylruthenium hexafluorophosphate | 406502-50-9

• 英文名称: (η5-1-trifluoromethyl-2,3,4,5-tetramethylcyclopentadienyl)bis(acetonitrile)monocarbonylruthenium hexafluorophosphate
• CAS: 406502-50-9
• 化学式: C₁₅H₁₈F₃N₂ORu*F₆P
• 分子量: 545.35
• InChiKey: IKDIAPNXFTZDFD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (η5-1-trifluoromethyl-2,3,4,5-tetramethylcyclopentadienyl)tris(acetonitrile)ruthenium hexafluorophosphate 、 一氧化碳 以 二氯甲烷 为溶剂， 以70%的产率得到(η5-1-trifluoromethyl-2,3,4,5-tetramethylcyclopentadienyl)bis(acetonitrile)monocarbonylruthenium hexafluorophosphate
  参考文献：
  名称：

  A Facile Route to 1-Trifluoromethyl-2,3,4,5-tetramethylcyclopentadienyl Ruthenium Half- and Mixed-Sandwich Compounds

  摘要：

  A series of half and mixed-sandwich (Cpdouble dagger = 1-trifluoromethyl-2,3,4,5-tetramethylcyclopentadienide) ruthenium compounds have been synthesized from a new Cpdouble daggerRu synthon, [Cpdouble daggerRu(NCCH3)(3)](PF6). [Cpdouble daggerRu(NCCH3)(3)](PF6) is efficiently generated by photolysis of [Cpdouble daggerRuBz](PF6) in acetonitrile with a quantum yield of approximately 0.34. The methods described here should be useful for the synthesis of other compounds that contain the Cpdouble daggerRu group.

  DOI：

  10.1021/om010863g