[Fe(CO)4(1-(3,5-dimethylphenyl)-6,8,9-trimethyl-9-phosphafluorene)] | 905292-25-3

• 英文名称: [Fe(CO)4(1-(3,5-dimethylphenyl)-6,8,9-trimethyl-9-phosphafluorene)]
• CAS: 905292-25-3
• 化学式: C₂₇H₂₃FeO₄P
• 分子量: 498.298
• InChiKey: NVDIBQQNPCTGKI-VQGHGNOBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  diiron nonacarbonyl 、 1-(3,5-dimethylphenyl)-6,8,9-trimethyl-9-phosphafluorene 以 苯 为溶剂， 以76%的产率得到[Fe(CO)4(1-(3,5-dimethylphenyl)-6,8,9-trimethyl-9-phosphafluorene)]
  参考文献：
  名称：

  Facile Synthesis of Unsymmetrical 9-Phospha- and 9-Arsafluorenes

  摘要：

  Unsymmetrical 9-chloro-9-phosphafluorenes (dibenzophospholes) and 9-chloro-9-arsafluorenes (dibenzoarsoles) have been obtained by simple thermolysis of m-terphenyldichlorophosphines and -arsines in close to quantitative yields. The reaction temperatures are about 200 degrees C for the phosphines and 140 degrees C for the arsine, and the reactions are complete within 5 min. Alternatively, these compounds can be synthesized through an AlCl3-catalyzed Friedel Crafts type ring-closure reaction at low temperatures, but this method suffers from difficult workup procedures. The P(As)-Cl functionality is readily alkylated. Methylation of m-xylyl derivative 4 afforded 1-(3,5-dimethylphenyl)-6,8,9 trimethyl-9-phosphafluorene, 11. The latter compound formed the complexes 11, Fe(CO)(4), 12, and 11 center dot RuCl2(eta(6)-p-cymene), 13, indicating its good donor properties. The new compounds have been characterized by H-1, C-13 {1H}, and P-31 {H-1} NMR spectroscopy; mass spectrometry; and single-crystal X-ray crystallography in the case of 11, 12, and 13.

  DOI：

  10.1021/ic051976l