| 133895-38-2

• CAS: 133895-38-2
• 化学式: C₃₈H₄₂Fe₂N₂Sn
• 分子量: 757.169
• InChiKey: WYAZETFCPPJYBM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N-dimethylaminomethylferrocene, monolithium salt 、 二苯基二氯化锡 以 四氢呋喃 为溶剂， 以73%的产率得到
  参考文献：
  名称：

  选自第 13 和 14 族元素的二甲基氨基甲基二茂铁基化合物的表示、性质和分子结构

  摘要：

  Dimethylmetalchlorides of gallium and indium react wi th dime thylaminomethylferrocenyllithium (FcNLi) to give the corresponding dimethylmetaldimethylaminomethylferrocenes 1 and 2 [Me(2)MFcN; M=Ga, In]. In a similar manner dialkylmetaldichlorides of germanium and tin yield the expected chlordialkylmetaldimethylaminomethylferrocenes 3-5 [R-2(Cl)MFcN; M=Ge; R=Me(3), M=Sn; R=Me (4), Ph (5)]. In a reaction of Me3Al and Me2AlCl with dimethylaminomethylferrocene the formation of the 1 : 1 adducts 7 and 8 could be observed. All compounds were characterised by H-1 and C-13 nmr spectroscopy. The molecular structures of 1, 3, 4 and 7 were determined. 3 and 4 build in contrast to 1 monomeric molecules with chelat rings as a result of the M-N coordination. Compound 7 consist of monomeric molecules with 4 coordinated Al atoms.

  DOI：

  10.1002/(sici)1521-3749(200003)626:3<759::aid-zaac759>3.0.co;2-9