| 252680-41-4

• CAS: 252680-41-4
• 化学式: C₃₂H₅₁Rh
• 分子量: 538.662
• InChiKey: YRWQEPVWZSCIHM-GHDUESPLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ferrocenium(III) tetrafluoroborate 、 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Rhodium-Promoted Linear Tetramerization and Cyclization of 3,3-Dimethylbut-l-yne

  摘要：

  With tetrahydrofuran as the solvent [Rh(thf)(2)(cod)](+) promotes the selective coupling of tBuC(2)H to form triene-yne 1; at high alkyne concentrations, however, an unusual C-H activation process intervenes, leading to the formation of complex 2, which contains two linked five-membered rings. cod=1,5-cyclooctadiene.

  DOI：

  10.1002/(sici)1521-3773(19991018)38:20<3043::aid-anie3043>3.0.co;2-2
• 作为产物：
  描述：

  bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 、 3,3-二甲基-1-丁炔 以 四氢呋喃 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Rhodium-Promoted Linear Tetramerization and Cyclization of 3,3-Dimethylbut-l-yne

  摘要：

  With tetrahydrofuran as the solvent [Rh(thf)(2)(cod)](+) promotes the selective coupling of tBuC(2)H to form triene-yne 1; at high alkyne concentrations, however, an unusual C-H activation process intervenes, leading to the formation of complex 2, which contains two linked five-membered rings. cod=1,5-cyclooctadiene.

  DOI：

  10.1002/(sici)1521-3773(19991018)38:20<3043::aid-anie3043>3.0.co;2-2