carbonyl(oxygen)meso-tetraphenylporphyrinatocobalt(II) | 52587-85-6

• 英文名称: carbonyl(oxygen)meso-tetraphenylporphyrinatocobalt(II)
• CAS: 52587-85-6
• 化学式: C₄₅H₂₈CoN₄O₃
• 分子量: 731.736
• InChiKey: KNEFPIGAVNZLBG-NBICUONBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cobalt(II) 5,10,15,20-tetraphenylporphyrin 、 一氧化碳 、 氧气 以 neat (no solvent) 为溶剂， 生成 carbonyl(oxygen)meso-tetraphenylporphyrinatocobalt(II)
  参考文献：
  名称：

  摘要：

  The interaction of carbon monoxide and dioxygen with low-temperature (T = 77 K) sublimates of cob alt(II) meso- tetraphenylporphyrinate (CoTPP) is studied by IR spectroscopy using is otopically labeled compounds ((CO)-C-13 and O-18(2)). The obtained data confirm the coordination of CO and O-2 with the formation of axial complexes CoTPP L (L = O-2, CO) and the mixed complex O-2 CoTPP CO. The heating of the complex containing CO and O-2 to 150 K leads to the appearance of lines in the IR spectrum corresponding to valence asymmetric (v(as)OCO) and degenerated deformation (delta OCO) vibrations of carbon dioxide. This is evidence for the oxidation of CO. The evacuation of CO2 at a higher, but still low, temperature and the addition of a new portion of CO and O-2 mixture lead to the formation of new portions of CO2. This demonstrates the catalytic character of the process. Only low-temperature sublimates have catalytic properties. Sublimates of CoTPP obtained on the surface at room or higher temperature demonstrate neither catalytic activity nor the ability to coordinate any amount of CO and O-2 sufficient for the detection by spectroscopy.

  DOI：

  10.1023/a:1010433905648