[Cp2Zr(C(propyl)C(propyl)C9H4N(COOEt)(COO))] | 816453-98-2

• 英文名称: [Cp2Zr(C(propyl)C(propyl)C9H4N(COOEt)(COO))]
• CAS: 816453-98-2
• 化学式: C₃₁H₃₃NO₄Zr
• 分子量: 574.831
• InChiKey: QHNMQZSZVZKDEE-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  Cp2ZrEt2 、 4-辛炔 、 2-溴苯腈 、 丁炔二酸二乙酯 在 copper(l) chloride 作用下， 以 四氢呋喃 为溶剂， 以61%的产率得到[Cp2Zr(C(propyl)C(propyl)C9H4N(COOEt)(COO))]
  参考文献：
  名称：

  Heterocyclized Carbometalation of Alkynes:  Unexpected Formation of Eight-Membered Oxazirconacycles with an Intramolecularly Coordinated Isoquinoline Moiety

  摘要：

  The isoquinolyl-zirconation of various unactivated alkynes was investigated by a one-pot, three-component reaction of two different alkynes with a nitrile in the presence of 1 equiv of CuCl. The true nature of the resulting products of novel eight-membered oxazirconacycles containing an intramolecular Zr-N coordination was established using X-ray crystallography.

  DOI：

  10.1021/om049302q