[Pt(N,N'-(1,10-phenanthroline-5,6-dione))Cl2] | 35244-62-3

• 英文名称: [Pt(N,N'-(1,10-phenanthroline-5,6-dione))Cl2]
• CAS: 35244-62-3
• 化学式: C₁₂H₆Cl₂N₂O₂Pt
• 分子量: 476.178
• InChiKey: LLQZSJYCXVHPPT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Pt(N,N'-(1,10-phenanthroline-5,6-dione))Cl2] 、 sodium tetrahydroborate 以 四氢呋喃 为溶剂， 生成 Na[Pt(N,N'-C12H6N2(O)2)Cl2]
  参考文献：
  名称：

  Electrochemical and spectroelectrochemical studies of complexes of 1,10-phenanthroline-5,6-dione

  摘要：

  Electrochemical and spectroelectrochemical (UV-Vis, IR, EPR) of pd (pd = 1,10-phenanthroline-5, 6-dione), Pt(N,N'-pd)Cl-2, Pd(N,N'-pd)Cl-2, [Ru(bpy)(2)(N,N'-pd)]Cl-2 (bpy = 2,2'-bipyridine) and Pt(O,O'-pd)(PPh3)(2), where N,N' and O,O' refers to coordination of pd to the metal centre via N and O atoms, respectively, reveals that the electron transfer processes between +0.5 and -1.25 V all occur at the pd ligand in agreement with DFT calculations. The two CO groups carry a significant amount of the negative charge in mono-reduced pd(1). The mode of coordination of pd has a greater influence on its redox chemistry than the metal centre or the ancillary ligands. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.050
• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 1,10-邻二氮杂菲-5,6-二酮 以 水 为溶剂， 以88 %的产率得到[Pt(N,N'-(1,10-phenanthroline-5,6-dione))Cl2]
  参考文献：
  名称：

  Biological activity of two water-soluble amino acid-Pt complexes: Synthesis, characterization, cytotoxicity, DNA interaction, and theoretical studies

  摘要：

  DOI：

  10.1016/j.inoche.2023.111477