[(μ-BuS)(η1-Ph2PS-η2)Fe2(CO)6)(μ4-S)Fe2(CO)5] | 833448-24-1

• 英文名称: [(μ-BuS)(η1-Ph2PS-η2)Fe2(CO)6)(μ4-S)Fe2(CO)5]
• CAS: 833448-24-1
• 化学式: C₂₇H₁₉Fe₄O₁₁PS₃
• 分子量: 870.001
• InChiKey: WJVJWJRHIKUYSA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  十二羰基三铁 、 (μ-dithio)bis(tricarbonyliron) 、 丁硫醇 、 二苯基氯化膦 在 n-BuLi 作用下， 以 四氢呋喃 为溶剂， 以42%的产率得到[(μ-BuS)(η1-Ph2PS-η2)Fe2(CO)6)(μ4-S)Fe2(CO)5]
  参考文献：
  名称：

  Unexpected Preparation of Butterfly Fe/S Cluster Complexes Containing a Quaternary Phosphorus Atom via Reactions of the Anions (μ-RS)(μ-S^-)Fe₂(CO)₆ and (μ-RS)(μ-S^-)[Fe₂(CO)₆]₂(μ₄-S) with Diphenylchlorophosphine

  摘要：

  Six new butterfly Fe/S cluster complexes, (mu-RS)(eta(1)-Ph2PS-eta(1))[Fe-2(CO)C-6] (3, R = Me; 5, R = Ph), (mu-RS)(eta(1)-Ph2PS-eta(1))[Fe-2(CO)(5)(Ph2PY)] (4, R = Me, Y = Cl; 6, R = Y = Ph), and (mu-RS)(eta(1)-Ph2PS-eta(2))[Fe-2(CO)(6)](mu(4)-S)[Fe-2(CO)(5)] (7, R = n-Bu; 8, R = Ph), were unexpectedly prepared by a "one-pot" synthetic method involving reactions of the in situ generated S-centered monoanions (mu-RS)(mu-S-)Fe-2(CO)(6) (1) and (mu-RS)(mu-S-)-[Fe-2(CO)(6)](2)(mu(4)-S) (2) with Ph2PCl. While the possible mechanisms for the unexpected reactions are suggested, the structures of products 3-8 have been fully characterized.

  DOI：

  10.1021/om049372x