| 1424002-32-3

• CAS: 1424002-32-3
• 化学式: C₄₈H₄₂Co₂O₁₂P₂
• 分子量: 990.788
• InChiKey: MVXOQXGFKWUQRG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  一氧化碳 、 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Hydrogenation of α-enaminoketones with cobalt phosphine-modified catalysts

  摘要：

  The synthesis of alpha-enamines and hydrogenation of these compounds were studied using cobalt-modified complexes. Cobalt complexes were characterized by H-1, C-13 and P-31 NMR, elemental analysis and IR spectroscopy. Furthermore, the molecular structures of complexes C1-C2 and C4-C5 have been determined by single-crystal X-ray diffraction. All cobalt complexes investigated were active catalysts for the hydrogenation reaction. The best catalytic activity was obtained with an ortho-substituent in the phosphine ligand. Noteworthy, the reduction was chemoselective over the double bond. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.catcom.2012.12.025