[SnPhCl2(bis(pyrazol-1-yl)acetate)] | 853294-75-4

• 英文名称: [SnPhCl2(bis(pyrazol-1-yl)acetate)]
• CAS: 853294-75-4
• 化学式: C₁₄H₁₂Cl₂N₄O₂Sn
• 分子量: 457.891
• InChiKey: VZFKCKUNJQOVAS-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  苯基三氯化锡 、 双(1-吡唑)乙酸 在 KOH 作用下， 以 甲醇 为溶剂， 以58%的产率得到[SnPhCl2(bis(pyrazol-1-yl)acetate)]
  参考文献：
  名称：

  Tin(IV) and organotin(IV) derivatives of bis(pyrazolyl)acetate: Synthesis, spectroscopic characterization and behaviour in solution.

  摘要：

  Novel heteroscorpionate-containing tin and organotin(IV) complexes, [SnRnX3-n(L)], R = Me, Bu-n, Ph, or cy; X = Cl, Br or I, n = 0, 1, 2 or 3; L = bis(pyrazol-1-yl)acetate (bpza) or bis(3,5-dimethylpyrazol-1-yl)acetate (bdmpza), have been synthesized and characterized by spectral (IR, H-1, C-13 and Sn-119 NMR, Sn-119m Mossbauer) and analytical data. In [SnI3(bdmpza)], the ligand is fac-N,N',O-tridentate, the three iodine atoms thus also fac about the six-coordinate tin(IV) atom. Neutral bpzaH reacts with (BuSnCl3)-Sn-n, PhSnCl3 and SnCl4 in Et2O in the absence of base, yielding 1:1 adducts [XSnCl3(bpzaH)] (X = R or Cl). (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.01.067