| 917219-96-6

• CAS: 917219-96-6
• 化学式: C₃₂H₂₄N₉Ru*F₆P
• 分子量: 780.637
• InChiKey: GBNFTBVJBNVRMF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  5-phenyltetrazole 、 六氟磷酸银 、 2,2'-bipyridine(2,2':6',2''-terpyridine)chlororuthenium(II) hexafluorophosphate 在 ammonium hexafluorophosphate 作用下， 以 水 、 丙酮 为溶剂， 以52%的产率得到
  参考文献：
  名称：

  Ruthenium(II) Complexes Containing Tetrazolate Group:  Electrochemiluminescence in Solution and Solid State

  摘要：

  In this work, we report the results about the solution and solid-state phosphorescence emission properties of six Ru-II complexes containing various 5-substituted tetrazolate ligands. The photo-and electrochemiluminescence spectra of all compounds revealed a red shifted emission with respect to the Ru(bpy)(3)(2+). Significant changes to the light emission energy and to the efficiency and sensitivity to oxygen were also determined by varying the nature of the substituent ring of the tetrazolate ligand. Light-emitting solid devices with active layers containing solid films of the same complexes were prepared, and preliminary studies of their electroinduced emission properties were performed. The electrochemiluminescence (ECL) emission intensity of two of the six complexes was of the same order of magnitude as the reference Ru(bpy)(3)(2+).

  DOI：

  10.1021/jp064326r