trans-((eta.5-cyclopentadienyl)(carbonyl)2(triphenylphosphine)molybdenum) tetrafluoroborate | 78833-68-8

• 英文名称: trans-((eta.5-cyclopentadienyl)(carbonyl)2(triphenylphosphine)molybdenum) tetrafluoroborate
• CAS: 78833-68-8
• 化学式: BF₄*C₄₃H₃₅MoO₂P₂
• 分子量: 828.442
• InChiKey: HTQRNCATFPJFFO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-((eta.5-cyclopentadienyl)(carbonyl)2(triphenylphosphine)molybdenum) tetrafluoroborate 以 乙腈 为溶剂， 生成 (η-C5H5)Mo(CO)3(PPh3)BF4
  参考文献：
  名称：

  95Mo NMR investigation on cationic [C5H5Mo(CO)2L2]BF4 complexes (L = group 15 donor ligands

  摘要：

  Photochemically-initiated oxidative fission of the Mo-Mo bond in [C5H5Mo(CO)3]2 by the ferricenium salt [(C5H5)2Fe]BF4 in the presence of four equivalents of L affords a good yield of [C5H5Mo(CO)2L2]BF4 (L = group 15 donor ligands). Mo-95 NMR data are reported and discussed together with the NMR and IR data of new complexes. Decomposition of the title cations in polar solvents affords low yields of the corresponding [C5H5Mo(CO)3L]BF4 complexes. The X-ray crystal structure of [C5H5Mo (CO)3{P(C6H5)3}]BF4 is reported. The cation has the CpML4 piano-stool geometry.

  DOI：

  10.1016/s0277-5387(00)83752-3
• 作为产物：
  描述：

  ferrocenium(III) tetrafluoroborate 、 cyclopentadienylmolybdenum tricarbonyl dimer 在 PPh₃ 作用下， 以 1,2-二氯乙烷 为溶剂， 以>90的产率得到trans-((eta.5-cyclopentadienyl)(carbonyl)2(triphenylphosphine)molybdenum) tetrafluoroborate
  参考文献：
  名称：

  95Mo NMR investigation on cationic [C5H5Mo(CO)2L2]BF4 complexes (L = group 15 donor ligands

  摘要：

  Photochemically-initiated oxidative fission of the Mo-Mo bond in [C5H5Mo(CO)3]2 by the ferricenium salt [(C5H5)2Fe]BF4 in the presence of four equivalents of L affords a good yield of [C5H5Mo(CO)2L2]BF4 (L = group 15 donor ligands). Mo-95 NMR data are reported and discussed together with the NMR and IR data of new complexes. Decomposition of the title cations in polar solvents affords low yields of the corresponding [C5H5Mo(CO)3L]BF4 complexes. The X-ray crystal structure of [C5H5Mo (CO)3{P(C6H5)3}]BF4 is reported. The cation has the CpML4 piano-stool geometry.

  DOI：

  10.1016/s0277-5387(00)83752-3

文献信息

• Metallorganiche lewis-säuren; metallkomplexe mit schwach koordinierten liganden
  作者：Karlheinz Sünkel、Ulrich Nagel、Wolfgang Beck

  DOI：10.1016/s0022-328x(00)89153-6

  日期：1981.12
• Suenkel, Karlheinz; Ernst, Herbert; Beck, Wolfgang, Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1981, vol. 36, # 4, p. 474 - 481
  作者：Suenkel, Karlheinz、Ernst, Herbert、Beck, Wolfgang

  DOI：——

  日期：——
• Markham; Menard; Cutler, Inorganic Chemistry, 1985, vol. 24, # 10, p. 1581 - 1587
  作者：Markham、Menard、Cutler

  DOI：——

  日期：——
• Photochemisch initiierte oxidative spaltung von [C5H5Mo(CO)3]2; ein einfacher zugang zu kationischen komplexen des typs [C5H5Mo(CO)2L2]BF4
  作者：Hans Schumann

  DOI：10.1016/0022-328x(87)80368-6

  日期：1987.4
• Synthetic applications of the oxidative cleavage of the molybdenum-mercury bonds in [CpMo(CO)2(PPh3)]2Hg
  作者：Chen C. Lin、Suzie Hathcox、Stephen L. Gipson

  DOI：10.1016/s0020-1693(00)80467-3

  日期：1990.4