(η(5)-cyclopentadienyl-CO2Me)2Mo2(CO)2(μ-SePh)2 | 197173-00-5

• 英文名称: (η(5)-cyclopentadienyl-CO2Me)2Mo2(CO)2(μ-SePh)2
• CAS: 197173-00-5
• 化学式: C₂₈H₂₄Mo₂O₆Se₂
• 分子量: 806.295
• InChiKey: MBPHFGQZAZUOAW-UHFFFAOYSA-L

反应信息

• 作为反应物：
  描述：

  selenium 、 (η(5)-cyclopentadienyl-CO2Me)2Mo2(CO)2(μ-SePh)2 以 四氢呋喃 为溶剂， 以30%的产率得到trans/anti-(η(5)-cyclopentadienyl-CO2Me)2Mo2(CO)2(μ-SePh)2(μ-Se)2
  参考文献：
  名称：

  Synthesis and characterization of doubly bonded and quadruply bridged trans/anti and trans/syn-(η5-RC5H4)2M2(μ-Se)2(μ-SePh)2(M=Mo, W) isomers

  摘要：

  Reactions of a mixture of doubly bonded and double-bridged trans/anti and translsyn-(eta(5)-RC5H4)(2)M-2(CO)(2)(mu-SePh)(2) isomers with elemental selenium afford a series of novel doubly bonded and quadruply bridged isomers, trans/anti- (eta(5)-RC5H4)(2)M-2(mu-Se)(2)(mu-SePh)(2) (1a, M=Mo, R=H; 2a, M=Mo, R=MeO2C; 3a, M=Mo, R=EtO2C; 4a, M=W, R=MeO2C; 5a, M=W, R=EtO2C) and trans/syn-(eta(5)- RC5H4)(2)M-2(mu-Se)(2)(mu-SePh)(2) (1b, M=Mo, R=H; 2b, M=Mo, R=MeO2C; 3b, M=Mo, R=EtO2C; 4b, M=W, R=MeO2C; 5b, M=W, R=EtO2C). Such reactions were found to involve configuration inversions of the phenyl groups bonded to selenium atoms from syn to anti or vice versa. Thus, the reaction of single isomer trans/syn-(eta(5)-C5H5)(2)Mo-2(CO)(2)(mu-SePh)(2) with elemental selenium in tetrahydrofuran (THF) or toluene at reflux gave single trans/anti isomer 1a, whereas trans/anti-(eta(5)-EtO2CC5H4)(2)Mo-2(CO)(2)(mu-SePh)(2) reacted with selenium powder under similar conditions gave single trans/syn isomer 3b. Except for isomer 1b (previously prepared by another route), all of the above quadruply bridged isomers have been characterized by elemental analysis, MS, IR and H-1 NMR spectroscopies, as well as partly by C-13 NMR and Se-77 NMR spectroscopies. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00109-6
• 作为产物：
  描述：

  二苯基二硒醚 、 [(η(5)-CH3O2CC5H4)2Mo2(CO)4] 以57%的产率得到(η(5)-cyclopentadienyl-CO2Me)2Mo2(CO)2(μ-SePh)2
  参考文献：
  名称：

  Song, Li-Cheng; Shi, Yao-Cheng; Hu, Qing-Mei, Polyhedron, 1999, vol. 18, p. 19 - 24

  摘要：

  DOI：