[Cu2(triphenylphosphine)2(bis-diphenylphosphinomethane)Br2] | 1166001-43-9

• 英文名称: [Cu2(triphenylphosphine)2(bis-diphenylphosphinomethane)Br2]
• 英文别名: [Cu2(tpp)2(dppm)Br2]
• CAS: 1166001-43-9
• 化学式: C₆₁H₅₂Br₂Cu₂P₄
• 分子量: 1195.88
• InChiKey: ONRYKMQVFRMAFW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cu2(triphenylphosphine)2(bis-diphenylphosphinomethane)Br2] 以 neat (no solvent) 为溶剂， 生成 copper phosphide
  参考文献：
  名称：

  A phosphine complex of copper (I) bromide as single-source precursor for the aerosol-assisted chemical vapour deposition of phosphide

  摘要：

  A new homobimetallic complex [Cu-2(tpp)(2)(dppm)Br-2] (1) of copper(I) bromide with triphenylphosphine (tpp) and bis-diphenylphosphinomethane (dppm) has been synthesized and charaterized by m.p., elemental analysis, FT-IR, H-1 NMR, mass spectrometry, thermal studies and single crystal X-ray analysis. The solid-state molecular structure of 1, belonging to the monoclinic crystal system with space group P2(1)/n, describes it as a neutral dinuclear species in which two copper atoms are bridged together through two bromides and a dppm ligand and each copper atom possesses a distorted tetrahedral geometry. Complex 1 was studied as a single-source precursor for the fabrication of phase pure thin films of Cu3P by aerosol-assisted chemical vapour deposition. The films have been characterized by PXRD, SEM and ED-XRF analyses and found to exhibit the particles size range 200-400 nm with high purity and surface uniformity. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.01.031
• 作为产物：
  描述：

  三苯基膦 、 双二苯基膦甲烷 、 copper(I) bromide 以 四氢呋喃 为溶剂， 以85%的产率得到[Cu2(triphenylphosphine)2(bis-diphenylphosphinomethane)Br2]
  参考文献：
  名称：

  A phosphine complex of copper (I) bromide as single-source precursor for the aerosol-assisted chemical vapour deposition of phosphide

  摘要：

  A new homobimetallic complex [Cu-2(tpp)(2)(dppm)Br-2] (1) of copper(I) bromide with triphenylphosphine (tpp) and bis-diphenylphosphinomethane (dppm) has been synthesized and charaterized by m.p., elemental analysis, FT-IR, H-1 NMR, mass spectrometry, thermal studies and single crystal X-ray analysis. The solid-state molecular structure of 1, belonging to the monoclinic crystal system with space group P2(1)/n, describes it as a neutral dinuclear species in which two copper atoms are bridged together through two bromides and a dppm ligand and each copper atom possesses a distorted tetrahedral geometry. Complex 1 was studied as a single-source precursor for the fabrication of phase pure thin films of Cu3P by aerosol-assisted chemical vapour deposition. The films have been characterized by PXRD, SEM and ED-XRF analyses and found to exhibit the particles size range 200-400 nm with high purity and surface uniformity. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.01.031