fac-[Mn(4,5-dichloro-1-methylimidazole)(CO)3(2,2'-bipyridine)](1+) | 947273-25-8

• 英文名称: fac-[Mn(4,5-dichloro-1-methylimidazole)(CO)3(2,2'-bipyridine)](1+)
• CAS: 947273-25-8
• 化学式: C₁₇H₁₂Cl₂MnN₄O₃
• 分子量: 446.151
• InChiKey: FWMNTMHDVSBQBJ-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 fac-[Mn(4,5-dichloro-1-methylimidazole)(CO)3(2,2'-bipyridine)](1+) 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 以50%的产率得到
  参考文献：
  名称：

  Base-Promoted Tautomerization of Imidazole Ligands to N-Heterocyclic Carbenes and Subsequent Transmetalation Reaction

  摘要：

  Imidazole complexes of manganese(I) are transformed into their corresponding N-heterocyclic carbene derivatives by means of acid-base treatments; the subsequent sequential transmetalation reaction of the carbene to gold(I) proceeds through isolable heterometallic intermediate species.

  DOI：

  10.1021/ja073144n