[Pt(1,5-cyclooctadiene)(2-(2-trifluoromethyl)anilino-4,6-di-tert-butylphenol(-2H))] | 1101194-75-5

• 英文名称: [Pt(1,5-cyclooctadiene)(2-(2-trifluoromethyl)anilino-4,6-di-tert-butylphenol(-2H))]
• CAS: 1101194-75-5
• 化学式: C₂₉H₃₆F₃NOPt
• 分子量: 666.686
• InChiKey: FZCPRVCQZHNRDH-GHDUESPLSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  六氟磷酸银 、 [Pt(1,5-cyclooctadiene)(2-(2-trifluoromethyl)anilino-4,6-di-tert-butylphenol(-2H))] 以 四氢呋喃 为溶剂， 以83%的产率得到[Pt(1,5-cyclooctadiene)(2-(2-trifluoromethyl)anilino-4,6-di-tert-butylphenol(-2H))]PF6
  参考文献：
  名称：

  Redox Activation of Alkene Ligands in Platinum Complexes with Non-innocent Ligands

  摘要：

  The reactivity of metal olefin complexes with non-innocent ligands (NILs) was examined. Treatment of PtCl2(diene) with the deprotonated catechol or aminophenol ligands afforded the corresponding Pt(NIL)(diene) complexes. The Pt((t)BA(F)Ph)(COD), Pt((t)BA(F)Ph)(nbd), and Pt(O(2)C(6)H(2)(t)u(2))(COD) (H(2)(t)BA(F)Ph = 2-(2-trifluoromethyl)anilino-4,6-di-tert-butylphenol, (H2O2C6H2Bu2)-Bu-t = 3,5-di-tert-butylcatechol) complexes were examined by cyclic voltammetry. Treatment of Pt((t)BA(F)Ph)(COD) or Pt((t)BA(F)Ph)(nbd) with AgPF6 afforded the imino-semiquinones [Pt((t)BA(F)Ph)(COD)]PF6 or [Pt((t)BAFPh)(nbd)]PF6, respectively. The [Pt((t)BAFPh)(COD)] complex was unreactive toward nucleophiles, whereas the oxidized derivative, [Pt((t)BAFPh)(COD)]PF6, rapidly and stereospecifically added alkoxides at the carbon trans to the phenolate. The Pt((t)BA(F)Ph)(COD), [Pt((t)BA(F)Ph)(COD)]PF6, Pt((t)BA(F)Ph)(C8H12OMe), and [Cp2Co][Pt((t)BA(F)Ph)(C8H12OMe)] complexes were characterized crystallographically.

  DOI：

  10.1021/ic8017248
• 作为产物：
  描述：

  [Pt(1,5-cyclooctadiene)(2-(2-trifluoromethyl)anilino-4,6-di-tert-butylphenol(-2H))]PF6 在 Et₃N 作用下， 以 not given 为溶剂， 生成 [Pt(1,5-cyclooctadiene)(2-(2-trifluoromethyl)anilino-4,6-di-tert-butylphenol(-2H))]
  参考文献：
  名称：

  Redox Activation of Alkene Ligands in Platinum Complexes with Non-innocent Ligands

  摘要：

  The reactivity of metal olefin complexes with non-innocent ligands (NILs) was examined. Treatment of PtCl2(diene) with the deprotonated catechol or aminophenol ligands afforded the corresponding Pt(NIL)(diene) complexes. The Pt((t)BA(F)Ph)(COD), Pt((t)BA(F)Ph)(nbd), and Pt(O(2)C(6)H(2)(t)u(2))(COD) (H(2)(t)BA(F)Ph = 2-(2-trifluoromethyl)anilino-4,6-di-tert-butylphenol, (H2O2C6H2Bu2)-Bu-t = 3,5-di-tert-butylcatechol) complexes were examined by cyclic voltammetry. Treatment of Pt((t)BA(F)Ph)(COD) or Pt((t)BA(F)Ph)(nbd) with AgPF6 afforded the imino-semiquinones [Pt((t)BA(F)Ph)(COD)]PF6 or [Pt((t)BAFPh)(nbd)]PF6, respectively. The [Pt((t)BAFPh)(COD)] complex was unreactive toward nucleophiles, whereas the oxidized derivative, [Pt((t)BAFPh)(COD)]PF6, rapidly and stereospecifically added alkoxides at the carbon trans to the phenolate. The Pt((t)BA(F)Ph)(COD), [Pt((t)BA(F)Ph)(COD)]PF6, Pt((t)BA(F)Ph)(C8H12OMe), and [Cp2Co][Pt((t)BA(F)Ph)(C8H12OMe)] complexes were characterized crystallographically.

  DOI：

  10.1021/ic8017248