| 151605-37-7

• CAS: 151605-37-7
• 化学式: C₂₀H₄₄CuN₄Si₄*NO₃
• 分子量: 578.489
• InChiKey: XWODVGHVKDKVBC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) nitrate trihydrate 、 三甲基硅烷氰化甲烷 以 四氢呋喃 为溶剂， 以85%的产率得到
  参考文献：
  名称：

  Synthesis and characterization of copper and manganese complexes of monodentate functionalized isocyanide: trimethylsilylmethylisocyanide and p-tolylsulfonylmethylisocyanide

  摘要：

  Reaction of excess CNCH2SiMe3(L) with CuX2.nH2O (X=NO3-, n=3; ClO4-, n=6) in THF gives the Cu(I) complexes [CuL4]NO3 (1) and [CuL4]ClO4 (2). When CuCN is used as starting material, complex 3, Cu(L3)CN, C4H10O.3H2O, is obtained. Immediate reduction occurs with AgNO3 precipitating metallic Ag. Reactions with MnCl2.6H2O and Mn(NO3)2.6H2O in THF produce two new compounds which analyze as MnL4Cl2.4H2O (6) and MnL2(NO3)2.H2O (7). When excess p-tolylsulfonylmethylisocyanide (L') is reacted with Cu(NO3)2, the mixed-valence Cu(I)-Cu(II) complex Cu2L6'(NO3)3 (5) is Precipitated, while using CuCN gives the Cu(I) dimer Cu2L'4(CN)2 (4). In analogous conditions the manganese complex MnL'2(NO3)2.C3H6O.3H2O (8) is precipitated. All these complexes have been isolated, characterized by IR, NMR for diamagnetic species, magnetic susceptibilities, EPR measurements and electrochemical analyses. Influence of the two substituents is discussed.

  DOI：

  10.1016/s0020-1693(00)83319-8