InMe3*p-tolyl isocyanide | 352032-84-9

• 英文名称: InMe3*p-tolyl isocyanide
• CAS: 352032-84-9
• 化学式: C₁₁H₁₆InN
• 分子量: 277.075
• InChiKey: UNAKZKJJZKMWHC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  四氢吡咯 、 InMe3*p-tolyl isocyanide 以 正己烷 为溶剂， 生成
  参考文献：
  名称：

  Reactions of InMe3 with isocyanides in the presence of amines: chemical and mass spectrometric evidence of unprecedented insertion into InN bonds

  摘要：

  InMe3 reacts with CNR (R=C6H4-p-OMe, C6H4-p-Me) affording the corresponding adducts Me3InCNR, which are formed even in the presence of an excess of CNR. Me3InCNR reacts with pyrrolidine to give the [Me2InC(=NR)(Pyrr)] products [Pyrr = conjugated base of pyrrolidine], which form through the insertion of CNR into the In-N-Pyrr bond. These insertion products decompose easily to give the corresponding formamidines. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00649-0
• 作为产物：
  描述：

  4-甲苯基异腈 、 三甲基铟 以 正己烷 为溶剂， 以87%的产率得到InMe3*p-tolyl isocyanide
  参考文献：
  名称：

  Reactions of InMe3 with isocyanides in the presence of amines: chemical and mass spectrometric evidence of unprecedented insertion into InN bonds

  摘要：

  InMe3 reacts with CNR (R=C6H4-p-OMe, C6H4-p-Me) affording the corresponding adducts Me3InCNR, which are formed even in the presence of an excess of CNR. Me3InCNR reacts with pyrrolidine to give the [Me2InC(=NR)(Pyrr)] products [Pyrr = conjugated base of pyrrolidine], which form through the insertion of CNR into the In-N-Pyrr bond. These insertion products decompose easily to give the corresponding formamidines. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00649-0