(NBu4)([Ph3BP(m-iPr2)]Mo(CO)5) | 651329-99-6

• 英文名称: (NBu4)([Ph3BP(m-iPr2)]Mo(CO)5)
• CAS: 651329-99-6
• 化学式: C₁₆H₃₆N*C₃₅H₃₃BMoO₅P
• 分子量: 913.837
• InChiKey: QKTPLMFDQFQYRI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [3-di(propan-2-yl)phosphanylphenyl]-triphenylboranuide;tetrabutylazanium 、 molybdenum hexacarbonyl 以 四氢呋喃 为溶剂， 生成 (NBu4)([Ph3BP(m-iPr2)]Mo(CO)5)
  参考文献：
  名称：

  Coordinating Anions:  (Phosphino)tetraphenylborate Ligands as New Reagents for Synthesis

  摘要：

  Anionic, electron-releasing phosphines that incorporate a borate counteranion within the ligand framework are promising reagents for organometallic catalysis. This report describes the synthesis of a new class of monodentate tertiary phosphines built upon the commonly employed tetraphenylborate anion. These new phosphines are highly stable and strongly electron-releasing and readily coordinate transition metals. Moreover, they are promising reagents for catalysis, as demonstrated by their ability to promote the Suzuki cross-coupling of aryl chloride substrates.

  DOI：

  10.1021/ic0350234