μ-π-η(1):η(1)-(C,N);η(1)(Npy);η(1)(N'py)-Fe2(CO)6(CH3C5H3NCHNNCHC5H3NCH3) | 915787-76-7

• 英文名称: μ-π-η(1):η(1)-(C,N);η(1)(Npy);η(1)(N'py)-Fe2(CO)6(CH3C5H3NCHNNCHC5H3NCH3)
• CAS: 915787-76-7
• 化学式: C₂₀H₁₄Fe₂N₄O₆
• 分子量: 518.048
• InChiKey: UABXAQDVMNWJRT-CPWWVIHGSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  diiron nonacarbonyl 、 1,4-di(6-methyl-2'-pyridyl)-2,3-diaza-1,3-butadiene 以 四氢呋喃 为溶剂， 以94%的产率得到μ-π-η(1):η(1)-(C,N);η(1)(Npy);η(1)(N'py)-Fe2(CO)6(CH3C5H3NCHNNCHC5H3NCH3)
  参考文献：
  名称：

  Reactions of diiron nonacarbonyl with pyrrolyl-, pyridyl- and thienyl-substituted azines: NN bond cleavage, cyclometallation and CN σ and π-bonding

  摘要：

  The reactions of 1,4-di-(N-methyl-2'-pyrrolyt)-2,3-diaza-1,3-butadiene (1), 1,4-di-(6-methyl-2-pyridyl)-2,3-diaza-1,3-butadiene (2) and 3,6-di-(2'-thienyt)-1,2,4,5-tetrazine (3) with Fe-2(CO)(9) in toluene, THF and benzene, respectively, yielded various types of hexacarbonyldiiron complexes with five different coordination modes: (1) a complex with two 2-pyrrolylmethylideneamido bridging ligands, 1a, which resulted from N-N bond cleavage of ligand 1, (2) a cyclometallated (mu-2,3-eta(1):eta(2)-pyrrolyl; eta(1):eta(1)(N)) complex 1b and a cyclometallated (mu-2,3-eta(1):eta(2)-thienyl; eta(1):eta(1)(N)) complex 3b, (3) a diaza-bridged complex 3a, (4) an imine-bridged (mu-sigma;pi-eta(1):eta(2)-(C,N); eta(1)(N-py)) complex 2a and (5) an imine-bridged (mu-pi-eta(1):eta(1)-(C, N); eta(1) (N-py); eta(1)(N'(py))) complex 2b. The molecular structures of the ligands 1 and 3 as well as of the complexes 1a, 2a and 3a have been determined by single-crystal X-ray crystallography. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.04.031