| 705251-04-3

• CAS: 705251-04-3
• 化学式: C₃₁H₃₉ClCuN₂
• 分子量: 538.663
• InChiKey: OQDWFJZRUQVGOE-PBFIREBQSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  o-C6H4(NH(C6H3(i)Pr2-2,6)(CH=NC6H3(i)Pr2-2,6) 、 copper dichloride 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 1.0h， 以76.7%的产率得到
  参考文献：
  名称：

  Cu(II) complexes with anilido-imine ligands: Synthesis, characterization and catalysis on reverse atom transfer radical polymerization of styrene

  摘要：

  Several copper(II) complexes bearing bidentate anilido-imine ligands [(Ar ' N=CHC6H4-NAr)Cu](2)(mu-Cl)(2) (Ar = Ar ' = 2,6-Me2C6H3 (1a); Ar = Ar ' = 2,6-Et2C6H3 (1b); Ar = 3,5-(CF3)(2)C6H3, Ar ' = 2,6-(Pr2C6H3)-Pr-1 (1d); Ar = p-OMeC6H4, Ar ' = 2,6-(Pr2C6H3)-Pr-i (le)), (Ar ' N=CHC6H4-NAr)CuCI (Ar = Ar ' = 2,6-(Pr2C6H3)-Pr-i (1c)), and that bearing tridentate quinolinyl anilido-imine ligand (2,6-(i)pr(2)C(6)H(3)N=CHC6H4-NAr)CuCI (Ar = 8-quinolinyl (1f)) were synthesized via reactions of the corresponding ligands with (BuLi)-Bu-n and subsequent in-situ addition of CuCl2. The X-ray diffraction analysis revealed that la and ld are dinuclear, while 1f with N,N,N-tridentate ligand is in monomeric form. In the presence of 2,2 '-azobisisobutyronitrile (AIBN), these well-defined complexes showed moderate to high activities in reverse ATRP of styrene. High conversions up to 86.5% were obtained and polymers with controllable molecular weight and relatively narrow polydispersity were produced. (C) 2017 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2017.01.018