[Ru(cyclopentadienyl)(PPh3)(dibenzyldithiomaleonitrile)][PF6] | 163491-60-9

• 英文名称: [Ru(cyclopentadienyl)(PPh3)(dibenzyldithiomaleonitrile)][PF6]
• CAS: 163491-60-9
• 化学式: C₄₁H₃₄N₂PRuS₂*F₆P
• 分子量: 895.874
• InChiKey: ASBCPRVNWLCLHN-BCUUCPOWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 二(三苯基膦)环戊二烯基氯化钌(II) 、 [Ru(cyclopentadienyl)(PPh3)(dibenzyldithiomaleonitrile)][PF6] 以 甲醇 为溶剂， 以70%的产率得到[Ru2(cyclopentadienyl)2(PPh3)3(μ(η(2)-S,S';η(1)-N)-dibenzyldithiomaleonitrile)][PF6]2
  参考文献：
  名称：

  Synthesis, spectral and electrochemical aspects of maleonitriledithiolate and dibenzyldithiomaleonitrile complexes of cyclopentadienylruthenium(II)

  摘要：

  Complexes [RuCp(PPh(3){S2C2(CN)(2)}](-) (1), [Ru(2)Cp(2)(PPh(3))(4){S2C2(CN)(2)}] (2) and [RuCp(PPh(3)){S-2(CH2C6H5)(2)C-2(CN)(2)}](+) (3) have been synthesized by the reaction of [CpRu(PPh(3))(2)Cl] with S2C2(CN)(2)(2-) or (C6H5CH2)(2)S2C2(CN)(2)] in MeOH. The complex [RuCp(PPh(3)){S-2(CH2-C6H5)(2)C-2(CN)(2)}](+) when further reacted with [CpRu(PPh(3))(2)Cl] formed a dinuclear complex [Ru(2)Cp(2)(PPh(3))(3){S-2(CH2C6H5)(2)C-2(CN)(2)}](2+) (4). All these complexes have been characterized by their physical and spectral (IR; H-1 P-31 NMR and visible spectral data. S2C2(CN)(2)(2-) has been found to introduce a low lying MLCT absorption in the electronic spectra of its complexes. In CV scan these complexes exhibit an extended series of one electron transfer reactions. The metal-centred oxidation waves of the complexes have been correlated with the pi acidity of ligands.

  DOI：

  10.1016/0022-328x(94)05034-9
• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 二(三苯基膦)环戊二烯基氯化钌(II) 、 1,2-bis(benzylthio)maleonitrile 以 甲醇 为溶剂， 以80%的产率得到[Ru(cyclopentadienyl)(PPh3)(dibenzyldithiomaleonitrile)][PF6]
  参考文献：
  名称：

  Prasad, R.; Prasad, S.; Agrwala, U. C., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1995, vol. 25, p. 1493 - 1506

  摘要：

  DOI：