(4,4'-bipyridyl)(1+)[dimethyltin-chloride dicyanoethylene-1,2-dithiolate](1-) | 710338-59-3

• 英文名称: (4,4'-bipyridyl)(1+)[dimethyltin-chloride dicyanoethylene-1,2-dithiolate](1-)
• CAS: 710338-59-3
• 化学式: C₆H₆ClN₂S₂Sn*C₁₀H₉N₂
• 分子量: 481.617
• InChiKey: QLVQAQNWYALJRH-BQRHYOBJSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4,4'-联吡啶 、 二甲基二氯化锡 、 disodium cis-1,2-dicyano-1,2-ethylenedithiolate 以 乙醇 为溶剂， 以83%的产率得到(4,4'-bipyridyl)(1+)[dimethyltin-chloride dicyanoethylene-1,2-dithiolate](1-)
  参考文献：
  名称：

  Synthesis and crystal structures of diorganotin dicyanoethylene-1,2-dithiolate compounds and their derivatives with 4,4′-Bipy or Phen

  摘要：

  Six diorganotin(IV) compounds with dicyanoethylene-1,2-dithiolate (mnt) of the type [R2Sn(mnt)ClnL] . Y (when n = 0, L = 0: R = CH3, y = 0, 1; R = n-Bu, Y = 0, 2; R = C6H6, Y = 0.5C(6)H(6), 3; R = CH3, Y = 1,5(4,4'-Bipy), 4; when n = 1, L = 0, R = CH3, Y = 4,4'-Bipy 5; when n = 0, L = Phen, R = CH3, Y = 0, 6; 4,4-Bipy = 4,4'-bipyridyl; Phen = 1,10-phenanthroline) are synthesized by the reaction of diorganotin dichloride and disodium maleonitriledithiolate (Na(2)mnt) in the presence of 4,4'-Bipy or Phen. All the compounds 1-6 are characterized by elemental, IR, H-1 NMR spectroscopy and X-ray crystallography analyses. The X-ray data showed the geometries of all the tin atoms in compounds 1-4 are tetrahedral, and those in 5 and 6 are trigonal bipyramidal and distorted octahedral, respectively. Co-crystallization is found in crystals of compounds 3 and 4. The co-crystallized solvents are benzene and 4,4'-Bipy, respectively. Compound 5 is a stannate with a five-coordinated tin(IV) atom. Compound 6 is a six-coordinated dimethyltin(IV) derivative from mixed ligands of mnt and Phen. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.01.019