dimethylbis(N-nitroso-N-phenyl-hydroxylaminato)tin(IV) | 260367-74-6

• 英文名称: dimethylbis(N-nitroso-N-phenyl-hydroxylaminato)tin(IV)
• CAS: 260367-74-6
• 化学式: C₂₈H₃₂N₈O₈Sn₂
• 分子量: 846.031
• InChiKey: MNOQIQWSORLRJW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2,4-二氨基-6-苯基-1,3,5-三嗪 、 dimethylbis(N-nitroso-N-phenyl-hydroxylaminato)tin(IV) 以 甲醇 为溶剂， 以66.6%的产率得到bis(N-nitroso-N-phenyl-hydroxylaminato)methanolato-dimethyltin(IV) 2,6-diamino-4-phenyl-1,3,5-triazine
  参考文献：
  名称：

  Heptacoordinate Dimethyltin(IV)cupferronato Complexes − X-ray and Solid-State NMR Structural Analysis − Hydrogen Bond Supramolecular Self-Assembly

  摘要：

  DOI：

  10.1002/1099-0682(200111)2001:11<2849::aid-ejic2849>3.0.co;2-u
• 作为产物：
  描述：

  tetrakis[trimethyl(N-nitroso-N-phenyl-hydroxylaminato)]tin(IV) 以 melt 为溶剂， 生成 dimethylbis(N-nitroso-N-phenyl-hydroxylaminato)tin(IV)
  参考文献：
  名称：

  Demethylation of the [Me3Sn(PhN2O2)]4 tetramer into dimeric [Me2Sn(PhN2O2)2]2: a thermally induced methyl-transfer between supramolecules

  摘要：

  The single crystals of tetrameric [Me3Sn(PhN2O2)]4 (1) supramolecule demethylates into single crystals of [Me2Sn(PhN2O2)2]2 dimer (2) and volatile Me4Sn, as a result of a crystal-to-crystal supramolecular structural transformation, which occurs upon heating and it is accompanied by a significant change of the molecular and crystal structures.

  DOI：

  10.1039/b506728f

文献信息

• Synthesis and Structural Characterization of Tin(IV)N-nitroso-N-phenylhydroxylaminato Complexes: Crystal Structures of Sn(O2N2Ph)4, Ph2Sn(O2N2Ph)2 and [Me2Sn(O2N2Ph)2]2
  作者：Andrea Deák、Monica Venter、Alajos Kálmán、László Párkányi、Lajos Radics、Ionel Haiduc

  DOI：10.1002/(sici)1099-0682(200001)2000:1<127::aid-ejic127>3.0.co;2-q

  日期：2000.1