| 827609-96-1

• CAS: 827609-96-1
• 化学式: C₇₄H₇₂Cl₂O₂P₄Rh₂S₄
• 分子量: 1522.26
• InChiKey: JFNRTURXVSNCKE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 neat (no solvent) 为溶剂， 生成 Rh₂(((C₆H₅)2PC₂H₄S)2C₆(CH₃)4)(((C₆H₅)2PC₂H₄S)2C₆H₄)⁽²⁺⁾*2Cl^(1-)=Rh₂(((C₆H₅)2PC₂H₄S)2C₆(CH₃)4)((C₆H₅)4P₂C₁₀H₁₂S₂)Cl₂
  参考文献：
  名称：

  Heteroligated Metallomacrocycles Generated via the Weak-Link Approach

  摘要：

  Sequential reaction of two different hemilabile ligands (Ph2PCH2-CH2X)(2)Ar (X = S, Ar = C6H4 or C-6(CH3)(4); X = NCH3, Ar = C6H4; X = O, Ar = 9,10-C14H8) with a Rh(I) metal center resulted in the formation of heteroligated metallomacrocycles in high yield. The specific reaction conditions for each pair of hemilabile ligands are discussed. The solid-state structure of [{1,4-(Ph2PCH2CH2S)(2)C6H4}-{1,4-(Ph2PCH2CH2S)(2)C-6(CH3)(4)}Rh-2](BF4)(2), as determined by X-ray crystallography, is presented.

  DOI：

  10.1021/ic048785n
• 作为产物：
  描述：

  、 一氧化碳 、 四甲基氯化铵 以 二氯甲烷 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Heteroligated Metallomacrocycles Generated via the Weak-Link Approach

  摘要：

  Sequential reaction of two different hemilabile ligands (Ph2PCH2-CH2X)(2)Ar (X = S, Ar = C6H4 or C-6(CH3)(4); X = NCH3, Ar = C6H4; X = O, Ar = 9,10-C14H8) with a Rh(I) metal center resulted in the formation of heteroligated metallomacrocycles in high yield. The specific reaction conditions for each pair of hemilabile ligands are discussed. The solid-state structure of [{1,4-(Ph2PCH2CH2S)(2)C6H4}-{1,4-(Ph2PCH2CH2S)(2)C-6(CH3)(4)}Rh-2](BF4)(2), as determined by X-ray crystallography, is presented.

  DOI：

  10.1021/ic048785n