[(Mn(CO)5)3Ga] | 137038-79-0

• 英文名称: [(Mn(CO)5)3Ga]
• CAS: 137038-79-0
• 化学式: C₁₅GaMn₃O₁₅
• 分子量: 654.693
• InChiKey: HCAVPDCLDZMWIC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium-manganese pentacarbonyl 、 Mes*GaCl2 以 乙醚 为溶剂， 生成 [(Mn(CO)5)3Ga]
  参考文献：
  名称：

  Cowley, Alan H.; Decken, Andreas; Olazábal, Claudia A., Inorganic Chemistry, 1994, vol. 33, # 16, p. 3435 - 3437

  摘要：

  DOI：

文献信息

• Campbell, Rachel M.; Clarkson, Lucy M.; Clegg, William, Chemische Berichte, 1992, vol. 125, # 1, p. 55 - 60
  作者：Campbell, Rachel M.、Clarkson, Lucy M.、Clegg, William、Hockless, David C. R.、Pickett, Nigel L.、Norman, Nicholas C.

  DOI：——

  日期：——
• Cp*GaCl2 and Cp*2GaCl (Cp*=η1-C5Me5) as starting materials for novel Group 13 element complexes
  作者：E Leiner、M Scheer

  DOI：10.1016/s0022-328x(01)01315-8

  日期：2002.3

  Reactions of Cp*GaCl2 and Cp-2*GaCl (Cp* = eta(1)-C5Me5), respectively, with different carbonylmetalate anions are compared to yield the transition-metal-gallium complexes [(eta(5)-Cp*Ga)W(CO)(5)] (1), [Fe-2(CO)(6)mu-(eta(5)-Cp*Ga)}(2)mu-(eta(3)-Cp*Ga)}] (2), [GaMn(CO)(5)}(3)] (3), [Cp-2*Ga(Mn(CO)(5)}] (4), [CO2(Co)(6)mu-(eta(5)-Cp*Ga)}(2)CO(CO)(3)] (5) and [(eta(5)-Cp)Fe(CO)}(2)(mu(2)-CO)mu(2)-(eta(5)-Cp*Ga}] (6), The results show that both starting materials offer an alternative synthetic route to subvalent Cp*Ga(l) compounds via reductive dehalogenation reactions in comparison to the previously used reactions starting from Cp*Ga itself. Starting from Cp*GaCl, Cp* elimination reactions are observed additionally, a process which dominates much more in the case of Cp*InCl2 as a starting material. In these reactions with [CpFe(CO)(2)](-) and [CPW(CO)(3)](-), [InCpFe(CO)(2)}(3)] (7) and [InCpW(CO)(3)}(3)] (8), respectively, are obtained in good yield. (C) 2002 Elsevier Science B.V. All rights reserved.