| 165965-60-6

• CAS: 165965-60-6
• 化学式: C₂₀H₉NO₁₁Os₃
• 分子量: 1009.89
• InChiKey: YMNRDJWZGYQEDM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  dicobalt octacarbonyl 、 以 正己烷 为溶剂， 以14%的产率得到
  参考文献：
  名称：

  A mixed Co- and Os-containingn,?-bicluster complex based on ?-phenylpropionitrile

  摘要：

  The PhCH(2)CH(2)CNOs(3)(CO)(11) complex was prepared by the reaction of OS3(CO)(12) with beta-cyanoethylbenzene, while the reaction with (CO)(3)CrPhCH(2)CH(2)CN gave a heterometallic derivative, (CO)(3)CrPhCH(2)CH(2)CNOs(3)(CO)(11). A bicluster complex, Co-4(CO)(9)PhCH(2)CH(2)CNOs(3)(CO)(11), was synthesized for the first time by the reaction of PhCH(2)CH(2)CNOs(3)(CO)(11) with Co-2(CO)(8); Co-4(CO)(9)PhCH(2)CH(2)CN was also obtained.

  DOI：

  10.1007/bf00699154
• 作为产物：
  描述：

  十二羰基三锇 、 苯代丙腈 在 十二/十四烷基二甲基氧化胺 作用下， 以 not given 为溶剂， 以74%的产率得到
  参考文献：
  名称：

  A mixed Co- and Os-containingn,?-bicluster complex based on ?-phenylpropionitrile

  摘要：

  The PhCH(2)CH(2)CNOs(3)(CO)(11) complex was prepared by the reaction of OS3(CO)(12) with beta-cyanoethylbenzene, while the reaction with (CO)(3)CrPhCH(2)CH(2)CN gave a heterometallic derivative, (CO)(3)CrPhCH(2)CH(2)CNOs(3)(CO)(11). A bicluster complex, Co-4(CO)(9)PhCH(2)CH(2)CNOs(3)(CO)(11), was synthesized for the first time by the reaction of PhCH(2)CH(2)CNOs(3)(CO)(11) with Co-2(CO)(8); Co-4(CO)(9)PhCH(2)CH(2)CN was also obtained.

  DOI：

  10.1007/bf00699154