[CoMo(μ-MeO2CC2H)(CO)5(η5-cyclopentadienyl)] | 126979-24-6

• 英文名称: [CoMo(μ-MeO2CC2H)(CO)5(η5-cyclopentadienyl)]
• CAS: 126979-24-6
• 化学式: C₁₄H₉CoMoO₇
• 分子量: 444.154
• InChiKey: QGAIRQXZJIJRFO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  dicobalt octacarbonyl 、 [CoMo(μ-MeO2CC2H)(CO)5(η5-cyclopentadienyl)] 以 甲苯 为溶剂， 以65%的产率得到[Co3Mo(μ4-HC2CO2Me)(CO)9(η5-cyclopentadienyl)]
  参考文献：
  名称：

  Rational synthesis of tricobalt-molybdenum and -tungsten butterfly clusters with alkyne ligands

  摘要：

  The heterometallic alkyne complexes [CoM(mu-R(1)Cequivalent toCR(2))(CO)(5)Cp] (M = Mo, W; R-1 = R-2 = CO2Me, CO2Et; R-1 = H, R-2 = CO2Me) react with dicobalt octacarbonyl in refluxing toluene to give the 60-electron tetranuclear clusters [Co3M(mu(4)-(RC2R2)-C-1 2)(CO)(9)Cp] in moderate to good yields. The clusters consist of a butterfly-type metal core in which the molybdenum (or tungsten) atom occupies a wing-tip position, as shown by X-ray analysis of three of the complexes. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01720-5
• 作为产物：
  描述：

  Na[Mo(CO)3Cp]*2(1,2-dimethoxyethane) 、 [Co2(μ-HCCO2Me)(CO)6] 以 四氢呋喃 为溶剂， 以66%的产率得到[CoMo(μ-MeO2CC2H)(CO)5(η5-cyclopentadienyl)]
  参考文献：
  名称：

  Rational synthesis of tricobalt-molybdenum and -tungsten butterfly clusters with alkyne ligands

  摘要：

  The heterometallic alkyne complexes [CoM(mu-R(1)Cequivalent toCR(2))(CO)(5)Cp] (M = Mo, W; R-1 = R-2 = CO2Me, CO2Et; R-1 = H, R-2 = CO2Me) react with dicobalt octacarbonyl in refluxing toluene to give the 60-electron tetranuclear clusters [Co3M(mu(4)-(RC2R2)-C-1 2)(CO)(9)Cp] in moderate to good yields. The clusters consist of a butterfly-type metal core in which the molybdenum (or tungsten) atom occupies a wing-tip position, as shown by X-ray analysis of three of the complexes. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01720-5

文献信息

• Albiez, Thomas; Bantel, Harald; Vahrenkamp, Heinrich, Chemische Berichte, 1990, vol. 123, p. 1805 - 1810
  作者：Albiez, Thomas、Bantel, Harald、Vahrenkamp, Heinrich

  DOI：——

  日期：——