[Os(κ2-dimethyldithiocarbamate)(SiMeCl2)(CO)(PPh3)2] | 895138-94-0

• 英文名称: [Os(κ2-dimethyldithiocarbamate)(SiMeCl2)(CO)(PPh3)2]
• CAS: 895138-94-0
• 化学式: C₄₁H₃₉Cl₂NOOsP₂S₂Si
• 分子量: 977.038
• InChiKey: ABMYONFWQYXGGC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Os(κ2-dimethyldithiocarbamate)(SiMeCl2)(CO)(PPh3)2] 、 potassium hydroxide 以 水 为溶剂， 以1%的产率得到[Os(κ2-dimethyldithiocarbamate)(Si(OH)3)(CO)(PPh3)2]
  参考文献：
  名称：

  The structurally characterised silyl complexes, Os(κ2-S2CNMe2)(SiMeCl2)(CO)(PPh3)2 and Os(κ2-S2CNMe2)(SiCl3)(CO)(PPh3)2, which have remarkably unreactive Si–Cl bonds

  摘要：

  Treatment Of Os(kappa(2)-S2CNMe2)H(CO)(PPh3)(2) with HSiMeCl2 or HSiCl3 gives in high yield Os(kappa(2)-S2CNMe2)(SiMeCl2)(CO)(PPh3)(2) (1) or Os(kappa(2)-S2CNMe2)(SiCl3)(CO)(PPh3)(2) (2), respectively. The crystal structures of both compounds have been determined and the Os-Si distances are 2.3672(10) angstrom for 1 and 2.3449(12) angstrom for 2. In solution, and under forcing conditions, both compounds are extraordinarily unreactive towards hydroxide ions. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.12.072
• 作为产物：
  描述：

  甲基二氯硅烷 、 [Os(κ2-dimethyldithiocarbamate)H(CO)(PPh3)2] 以 甲苯 为溶剂， 以70%的产率得到[Os(κ2-dimethyldithiocarbamate)(SiMeCl2)(CO)(PPh3)2]
  参考文献：
  名称：

  The structurally characterised silyl complexes, Os(κ2-S2CNMe2)(SiMeCl2)(CO)(PPh3)2 and Os(κ2-S2CNMe2)(SiCl3)(CO)(PPh3)2, which have remarkably unreactive Si–Cl bonds

  摘要：

  Treatment Of Os(kappa(2)-S2CNMe2)H(CO)(PPh3)(2) with HSiMeCl2 or HSiCl3 gives in high yield Os(kappa(2)-S2CNMe2)(SiMeCl2)(CO)(PPh3)(2) (1) or Os(kappa(2)-S2CNMe2)(SiCl3)(CO)(PPh3)(2) (2), respectively. The crystal structures of both compounds have been determined and the Os-Si distances are 2.3672(10) angstrom for 1 and 2.3449(12) angstrom for 2. In solution, and under forcing conditions, both compounds are extraordinarily unreactive towards hydroxide ions. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.12.072