| 192136-58-6

• CAS: 192136-58-6
• 化学式: C₁₇H₂₁N₂Zr*C₂₄H₂₀B
• 分子量: 663.825
• InChiKey: DFULPQOOMMWIHI-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  吡啶 、 Cp2Zr(NMe2)2 、 triethylammonium tetraphenylborate 以 四氢呋喃 为溶剂， 以93%的产率得到
  参考文献：
  名称：

  Synthesis of cationic Group 4 metal compounds by protonolysis of amide precursors: crystal structure of [Ti(NMe2)3(NC5H5)2][BPh4]

  摘要：

  Protonation of [M(NMe2)(4)] with NHEt3BPh4 in tetrahydrofuran (THF) gave the cationic compounds [M(NMe2)(3)(THF)(x)][BPh4] (M = Ti and x = 1; M = Zr or Hf and x = 2); similar treatment of [M(cp)(2)(NMe2)(2)] (M = Zr or Hf, cp = eta-C5H5) afforded the cations [M(cp)(2)(NMe2)(NMe2H)(1-x)(THF)(x)](+) which were transformed into [M(cp)(2)(NMe2)(NC5H5)](+) in pyridine. The trigonal bipyramidal crystal structure of [Ti(NMe2)(3)(NC5H5)(2)][BPh4] has been determined.

  DOI：

  10.1016/s0022-328x(96)06701-0