{N(C2H5)4}{Rh(CO)(P(C6H5)3)(η5-C2B9H9(CH3)2)} | 135157-57-2

• 英文名称: {N(C2H5)4}{Rh(CO)(P(C6H5)3)(η5-C2B9H9(CH3)2)}
• CAS: 135157-57-2
• 化学式: C₈H₂₀N*C₂₃H₃₀B₉OPRh
• 分子量: 683.922
• InChiKey: AIZXEPJDUNGYFP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  {N(C2H5)4}{Rh(CO)(P(C6H5)3)(η5-C2B9H9(CH3)2)} 在 HBF₄*(C₂H₅)2O 作用下， 以 二氯甲烷 为溶剂， 以72%的产率得到{RhH(CO)(P(C6H5)3)(η5-C2B9H9(CH3)2)}
  参考文献：
  名称：

  Carbaboranerhodium complexes with Rh–Rh, Rh–Cu and Rh–Au bonds; crystal structure of [NEt₄][Rh₂(µ-σ : η⁵-C₂B₉H₈Me₂)(CO)₃(η⁵-C₂B₉H₉Me₂)]

  摘要：

  The compound [NEt4][Rh(CO)(PPh3)(eta-5-C2B9H9Me2)] has been prepared and used to synthesise the dimetal complexes [RhM(CO)(PPh3)2(eta-5-C2B9H9Me2)] (M = Cu or Au) and [RhCu(CO)(PMe3)(PPh3)(eta-5-C2B9H9Me2)]. Protonation of [NEt4][Rh(CO)(PPh3)(eta-5-C2B9H9Me2)] gives an unstable hydride [RhH(CO)(PPh3)(eta-5-C2B9H9Me2)]. In contrast, treatment of [NEt4][Rh(CO)2(eta-5-C2B9H9Me2)] with HBF4.Et2O affords a dirhodium complex [Rh2(CO)3(eta-5-C2B9H9Me2)2] in which one carbaborane fragment bridges the Rh-Rh bond via an exopolyhedral B-H half-arrow-pointing-right Rh bond. This species can be deprotonated to give an anionic complex [Rh2(mu-sigma:eta-5-C2B9H8Me2)(CO)3(eta-5-C2B9H9Me2)]-, the [NEt4]+ salt of which may be obtained directly from [NEt4][Rh(CO)2(eta-5-C2B9H9Me2)] by treatment of the latter with [NHMe3]Cl. An X-ray crystallographic study established the structure of the anion. One rhodium centre is ligated by a CO molecule and by a C2B9H9Me2 cage in the normal eta-5 bonding mode, the other carries two CO groups and an eta-5-C2B9 cage. However, a boron atom beta to the carbons in the pentagonal open activated CCBBB face of this cage forms a sigma bond to the other rhodium atom [B-Rh 2.05(3) angstrom], so that this C2B9H9Me2 group bridges the Rh-Rh bond [2.876(3) angstrom]. The NMR data for the new compounds are reported and discussed.

  DOI：

  10.1039/dt9910001355
• 作为产物：
  描述：

  反式-双(三苯基膦)合氯化羰基铑(Ⅰ) 、 Tl₂[1,2-Me₂-1,2-closo-C₂B₉H₉] 、 四乙基氯化铵 以 四氢呋喃 为溶剂， 以60%的产率得到{N(C2H5)4}{Rh(CO)(P(C6H5)3)(η5-C2B9H9(CH3)2)}
  参考文献：
  名称：

  Carbaboranerhodium complexes with Rh–Rh, Rh–Cu and Rh–Au bonds; crystal structure of [NEt₄][Rh₂(µ-σ : η⁵-C₂B₉H₈Me₂)(CO)₃(η⁵-C₂B₉H₉Me₂)]

  摘要：

  The compound [NEt4][Rh(CO)(PPh3)(eta-5-C2B9H9Me2)] has been prepared and used to synthesise the dimetal complexes [RhM(CO)(PPh3)2(eta-5-C2B9H9Me2)] (M = Cu or Au) and [RhCu(CO)(PMe3)(PPh3)(eta-5-C2B9H9Me2)]. Protonation of [NEt4][Rh(CO)(PPh3)(eta-5-C2B9H9Me2)] gives an unstable hydride [RhH(CO)(PPh3)(eta-5-C2B9H9Me2)]. In contrast, treatment of [NEt4][Rh(CO)2(eta-5-C2B9H9Me2)] with HBF4.Et2O affords a dirhodium complex [Rh2(CO)3(eta-5-C2B9H9Me2)2] in which one carbaborane fragment bridges the Rh-Rh bond via an exopolyhedral B-H half-arrow-pointing-right Rh bond. This species can be deprotonated to give an anionic complex [Rh2(mu-sigma:eta-5-C2B9H8Me2)(CO)3(eta-5-C2B9H9Me2)]-, the [NEt4]+ salt of which may be obtained directly from [NEt4][Rh(CO)2(eta-5-C2B9H9Me2)] by treatment of the latter with [NHMe3]Cl. An X-ray crystallographic study established the structure of the anion. One rhodium centre is ligated by a CO molecule and by a C2B9H9Me2 cage in the normal eta-5 bonding mode, the other carries two CO groups and an eta-5-C2B9 cage. However, a boron atom beta to the carbons in the pentagonal open activated CCBBB face of this cage forms a sigma bond to the other rhodium atom [B-Rh 2.05(3) angstrom], so that this C2B9H9Me2 group bridges the Rh-Rh bond [2.876(3) angstrom]. The NMR data for the new compounds are reported and discussed.

  DOI：

  10.1039/dt9910001355

文献信息

• Chemistry of polynuclear metal complexes with bridging carbene or carbyne ligands. Part 112. Synthesis of rhenium–rhodium complexes; crystal structure of [ReRh{µ-σ,η⁵-C₂B₉H₇(CH₂C₆H₄Me-4)Me₂}(CO)₄(η-C₅H₄Me)]
  作者：Massimino U. Pilotti、F. Gordon A. Stone、Isil Topaloǧlu

  DOI：10.1039/dt9910001621

  日期：——

  aforementioned results the complex [Mn(CC6H4Me-4)(CO)2(η-C5H4Me)][BCl4] reacts with [NEt4][Rh(CO)(PPh3)(η5-C2B9H9Me2)] and [NEt4][Rh(cod)(η5-C2B9H9Me2)](cod = cycloocta-1,5-diene) to give the mononuclear rhodium species [Rhσ,η5-H(C6H4Me-4)C2B9H9Me2}(CO)(PPh3)] and [Rhσ,η5-CH(C6H4Me-4)C2B9H8Me2}(cod)], respectively. The NMR data (1H, 13C-1H}, 11B-1H}] for the new complexes are reported and discussed

  [净的治疗4 ]的[Rh（CO）2（η 5 -C 2乙9 ħ 9我2）]在CH 2氯2与[重（CC 6 H ^ 4 ME-4）（CO）2（η- ç 5 ħ 4 ME-4）] - [的BCl 4 ]，得到双金属配合物[ReRh μ-σ，η 5 -C 2乙9 ħ 7（CH 2 ç 6 ħ 4 ME-4）Me 2 }（CO ）4（η-C 5 H ^4 Me）]。通过X射线衍射确定结构。Re–Rh键[2.888（1）Å]横跨C 2 B 9 H 7（CH 2 C 6 H 4 Me-4）Me 2片段。的C的开放五边形面2乙9笼是η 5协调到铑，并且有一个exopolyhedral B-重新[2.17（2）]σ涉及在α位点的硼原子相对于键合[图中省略的图]环中的碳原子；β位的硼原子（图中省略）带有CH 2 C 6 H 4Me-4取代基。铼和铑原子各自被两个末端结合的CO分子连接，和铼也协调由η-C 5
• (Carbaborane)rhodium-copper and -manganese complexes: Crystal structure of [RhCu(PPh3)(cod)(η5-7,8-C2B9H9Me2)]
  作者：John C. Jeffery、F. Gordon、A. Stone、Isil Topalo>glu

  DOI：10.1016/0022-328x(93)83027-s

  日期：1993.6

  Treatment of [CuCl(PPh3)] with [NEt4][Rh(cod)(eta5-7,8-C2B9H9Me2)] (Cod = cyclo-octa-1,5-diene) in CH2Cl2 in the presence of TlBF4 affords the dimetal compound [RhCu(PPh3)(Cod)(eta5-7,8-C2B9H9Me2)], the structure of which has been established by X-ray diffraction (Rh-Cu 2.633(2) angstrom, Rb-Cu-P 153.3(1)-degrees). Reactions between [MnBr(CO)5] and the tetraethylammonium salts of the complexes [Rh(CO)(PPh3)(eta5-7,8-C2B9H9Me2)]- and [Rh(cod)(eta5-7,8-C2B9H9Me2)]- yield the dimetal compounds [MnRh(CO)5(L)(eta5 -7,8-C2B9H9Me2)] (L=PPh3 or CO) respectively. Treatment of [Mn(CO)2(NO)(eta5-C5H4Me)][BF4] with INEt4][Rh(CO)(PPh3)(eta5-7,8-C2B9H9Me2)] affords [Rh(NO)(PPh3)(eta5-7,8-C2B9H9Me2)], in an unusual reaction involving transfer of the NO ligand from manganese to rhodium.