η5-Cp'Mn(CO)3 | 104215-32-9

• 英文名称: η5-Cp'Mn(CO)3
• 英文别名: Mn(η(5)-C5HMe4)(CO)3；η⁵-Cp'Mn(CO)₃
• CAS: 104215-32-9
• 化学式: C₁₂H₁₃MnO₃
• 分子量: 260.171
• InChiKey: ICNMAJUSPVTAQA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,2,3,4,5-五甲基环戊二烯 、 羰基镁 生成 η5-Cp'Mn(CO)3
  参考文献：
  名称：

  HEMOND R. C.; HUGHES R. P.; LOCKER H. B., ORGANOMETALLICS, 5,(1986) N 11, 2391-2392

  摘要：

  DOI：

文献信息

• Synthesis and Structures of Triple-Decker Complexes with a Bridging Tetramethylcyclopentadienyl Ligand
  作者：Sonam K. Ghag、Michael L. Tarlton、Ernst A. Henle、Elizabeth M. Ochoa、Alex W. Watson、Lev N. Zakharov、Eric J. Watson

  DOI：10.1021/om301258s

  日期：2013.3.25

  New triple-decker complexes with bridging tetramethylcyclopentadienyl ligands were synthesized by the reaction of electrophilic metal fragments with octamethylferrocene, Cp-2'Fe (Cp' = C5Me4H). The reaction of coordinatively unsaturated ruthenium cations [(C5R5)Ru](+) (R = H, CH3) with Cp-2'Fe afforded purple-colored heterometallic triple-decker complexes [(C5R5)Ru(mu-Cp')-FeCp'](+) by direct electrophilic addition. Surprisingly, the analogous reaction with the coordinatively unsaturated manganese cation [Mn(CO)(3)](+) and Cp-2'Fe produced a blue homometallic triple-decker complex, [Cp'Fe(mu-Cp')FeCp'](+), by ring abstraction and subsequent addition of the newly generated cation [Cp'Fe] to an equivalent of Cp-2'Fe. Three air-stable triple-decker complexes, [Cp'Fe(mu-Cp')FeCp'](+) (2), [CpRu(mu-Cp')FeCp'](+) (3), and [Cp*Ru(mu-Cp')FeCp'](+)(4), have been characterized by NMR spectroscopy, elemental analysis, and single-crystal X-ray diffraction.
• Hemond, Richard C.; Hughes, Russell P.; Locker, Harry B., Organometallics, 1986, vol. 5, # 11, p. 2391 - 2392
  作者：Hemond, Richard C.、Hughes, Russell P.、Locker, Harry B.

  DOI：——

  日期：——