nido-5-ClCH2Si(CH3)2-2,3-(Si(CH3)3)2-2,3-C2B4H5 | 705256-40-2

• 英文名称: nido-5-ClCH2Si(CH3)2-2,3-(Si(CH3)3)2-2,3-C2B4H5
• CAS: 705256-40-2
• 化学式: C₁₁H₃₁B₄ClSi₃
• 分子量: 326.321
• InChiKey: ZVJJKXWBJQRSSG-PHIMTYICSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  1-lithia-2-phenyl-1,2-dicarba-closo-dodecaborane 、 nido-5-ClCH2Si(CH3)2-2,3-(Si(CH3)3)2-2,3-C2B4H5 以 乙醚 为溶剂， 以81%的产率得到1-Ph-2-[5'-CH2SiMe2-2',3'-(SiMe3)2-2',3'-C2B4H5]-1,2-C2B10H10
  参考文献：
  名称：

  Silyl group mediated linkage of closo-C2B10-cage to nido-C2B4-carborane: synthesis of the novel carborane ligand, 1-R-2-[5′-(SiMe2CH2)-2′,3′-(SiMe3)2-2′,3′-C2B4H5]-1,2-C2B10H10 (R=Me, Ph)

  摘要：

  The reaction of the sodium salt of the monoanion, nido-[2,3-(Si(CH3)(3))(2)-2,3-C2B4H5](-), with (chloromethyl)dimethylchlorosilane in a 1:1 molar ratio produced the B-(cage)-substituted cluster, nido-5-ClCH2Si(CH3)(2)-2,3-(Si(CH3)(3))(2)-2,3-C2B4H5 (1), in 81% yield. This product (1) was reacted further with the lithium salt of [closo-1-R-1,2-C2B10H10](-) monoanion (R =Me, Ph) to give the novel linked and mixed C2B4/C2B10 carborane species, 1-Me-2-[5'-SiMe2CH2-2',3'-(SiMe3)(2)-2',3-C2B4H5]-1,2-C2B10H10 (2), 1-Ph-2-[5'-SiMe2CH2-2',3'-(SiMe3)(2)-2',3'-C2B4H5]-1,2-C2B10 (3), in yields of 76% and 81%, respectively. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2003.07.002
• 作为产物：
  描述：

  2,3-bis(trimethylsilyl)-2,3-dicarba-nido-hexaborane(8) 、 氯甲基二甲基氯硅烷 、 sodium hydride 以 四氢呋喃 为溶剂， 以81%的产率得到nido-5-ClCH2Si(CH3)2-2,3-(Si(CH3)3)2-2,3-C2B4H5
  参考文献：
  名称：

  Silyl group mediated linkage of closo-C2B10-cage to nido-C2B4-carborane: synthesis of the novel carborane ligand, 1-R-2-[5′-(SiMe2CH2)-2′,3′-(SiMe3)2-2′,3′-C2B4H5]-1,2-C2B10H10 (R=Me, Ph)

  摘要：

  The reaction of the sodium salt of the monoanion, nido-[2,3-(Si(CH3)(3))(2)-2,3-C2B4H5](-), with (chloromethyl)dimethylchlorosilane in a 1:1 molar ratio produced the B-(cage)-substituted cluster, nido-5-ClCH2Si(CH3)(2)-2,3-(Si(CH3)(3))(2)-2,3-C2B4H5 (1), in 81% yield. This product (1) was reacted further with the lithium salt of [closo-1-R-1,2-C2B10H10](-) monoanion (R =Me, Ph) to give the novel linked and mixed C2B4/C2B10 carborane species, 1-Me-2-[5'-SiMe2CH2-2',3'-(SiMe3)(2)-2',3-C2B4H5]-1,2-C2B10H10 (2), 1-Ph-2-[5'-SiMe2CH2-2',3'-(SiMe3)(2)-2',3'-C2B4H5]-1,2-C2B10 (3), in yields of 76% and 81%, respectively. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2003.07.002