(η(4)-C(NMe2)=C(NMe2)-CH=C((t)Bu)-OCO)Fe(CO)3 | 168775-11-9

• 英文名称: (η(4)-C(NMe2)=C(NMe2)-CH=C((t)Bu)-OCO)Fe(CO)3
• CAS: 168775-11-9
• 化学式: C₁₆H₂₂FeN₂O₅
• 分子量: 378.208
• InChiKey: UACHWLIWDGFMQI-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (η(3)-C(NMe2)C(NMe2)=CH-CO-(t)Bu)Fe(CO)3 、 一氧化碳 以 1,2-二氯乙烷 为溶剂， 以81%的产率得到(η(4)-C(NMe2)=C(NMe2)-CH=C((t)Bu)-OCO)Fe(CO)3
  参考文献：
  名称：

  Reaction of a tert-Butyl-Substituted Iron(0) Alkynyl(ethoxy)carbene Complex with Dimethylamine

  摘要：

  The reaction of [(3,3-dimethylbutynyl)ethoxymethylene]Fe(CO)(4) (1) with dimethylamine was investigated. [(3,3-Dimethylbutynyl)(dimethylamino)methylene]-Fe(CO)(4) (2) was formed in. 95% yield by substitution of the ethoxy group at -78 degrees C. Meanwhile, the eta(3)-(2-(tertbutylcarbonyl)vinyl)carbene complete (3) was produced at 25 degrees C in 96% yield through the Michael-type addition of dimethylamine and subsequent rearrangements. The alkynyl(amino)carbene complex 2 was further reacted with dimethylamine in acetonitrile at 25 degrees C to give the eta(3)-vinylcarbene complex: 4 analogous to 3. Under CO pressure 3 and 4 were converted slowly to (eta(4)-alpha-pyrone)-Fe(CO)(3) complexes 5 and 6.

  DOI：

  10.1021/om00009a057